First Cyclic Carbodiphosphoranes of Copper(I) and Gold(I) and Their Application in the Catalytic Cleavage of X−H Bonds (X = N and O)
Impacte
Scholar |
Altres documents de l'autoria: Corberán Roc, Rosa; Marrot, Sebastien; Dellus, Nicolas; Merceron-Saffon, Nathalie; Kato, Tsuyoshi; Peris, Eduardo; Baceiredo, Antoine
Metadades
Mostra el registre complet de l'elementcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
comunitat-uji-handle4:
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http://dx.doi.org/10.1021/om8008958 |
Metadades
Títol
First Cyclic Carbodiphosphoranes of Copper(I) and Gold(I) and Their Application in the Catalytic Cleavage of X−H Bonds (X = N and O)Autoria
Data de publicació
2009Editor
American Chemical SocietyISSN
0276-7333Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
http://pubs.acs.org/doi/abs/10.1021/om8008958Resum
Three new carbodiphosphorane complexes, (PHCP)M(tBuO) (PHCP = carbodiphosphorane; M = Cu, Au) and (PHCP)CuCl, were readily prepared by reaction of the carbodiphosphorane 2 with CuCl or AuCl(Me2S). The three complexes ... [+]
Three new carbodiphosphorane complexes, (PHCP)M(tBuO) (PHCP = carbodiphosphorane; M = Cu, Au) and (PHCP)CuCl, were readily prepared by reaction of the carbodiphosphorane 2 with CuCl or AuCl(Me2S). The three complexes have been fully characterized, and their crystal structures have been determined. The two tert-butoxide complexes were tested in the catalytic anti-Markovnikov hydroamination and hydroalkoxylation of acrylonitrile, involving the first catalytic application of a carbodiphosphorane complex reported to date. [-]
Publicat a
Organometallics, 28, 1, p. 326–330Drets d'accés
Copyright © 2008 American Chemical Society
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