Unveiling the stereoelectronic properties of a triphenylene-based tris N-heterocyclic carbene
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Otros documentos de la autoría: Gonell, Sergio; Alabau, Roberto G.; Poyatos, Macarena; Peris, Eduardo
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http://dx.doi.org/10.1039/C3CC44109A |
Metadatos
Título
Unveiling the stereoelectronic properties of a triphenylene-based tris N-heterocyclic carbeneFecha de publicación
2013-06-14Editor
Royal Society of ChemistryISSN
1359-7345; 1364-548XCita bibliográfica
GONELL, Sergio, et al. Unveiling the stereoelectronic properties of a triphenylene-based tris N-heterocyclic carbene. Chemical Communications, 2013, vol. 49, no 64, p. 7126-7128Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://pubs.rsc.org/en/content/articlelanding/2013/cc/c3cc44109a#!divAbstractPalabras clave / Materias
Resumen
Two rhodium complexes with a triphenylene-based tris-NHC have been fully characterized. DFT and electrochemical studies suggest that the electronic communication between the metals is very weak, and that the electron ... [+]
Two rhodium complexes with a triphenylene-based tris-NHC have been fully characterized. DFT and electrochemical studies suggest that the electronic communication between the metals is very weak, and that the electron donating properties of the ligand are very similar to those shown by its benzimidazolylidene analogue. [-]
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Chemical Communications, 2013, vol. 49, no 64Derechos de acceso
© Royal Society of Chemistry 2014
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