A C3v-symmetrical tribenzotriquinacene-based threefold N-heterocyclic carbene. Coordination to rhodium(I) and stereoelectronic properties
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Scholar |
Otros documentos de la autoría: Segarra, Candela; Linke, Jens; Mas, Elena; Kuck, Dietmar; Peris, Eduardo
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Mostrar el registro completo del ítemcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7013
comunitat-uji-handle3:10234/8638
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http://dx.doi.org/10.1039/C3CC46155F |
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Título
A C3v-symmetrical tribenzotriquinacene-based threefold N-heterocyclic carbene. Coordination to rhodium(I) and stereoelectronic propertiesFecha de publicación
2013-09-19Editor
Royal Society of ChemistryISSN
1359-7345; 1364-548XCita bibliográfica
Chem. Commun., 2013, 49, 10572Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://pubs.rsc.org/en/content/articlelanding/2013/cc/c3cc46155f#!divAbstractVersión
info:eu-repo/semantics/publishedVersionPalabras clave / Materias
Resumen
A novel tribenzotriquinacene-based tris-NHC has been obtained and coordinated to rhodium. The new ligand displays a unique rigid C3v symmetry. The electrochemical analysis of the tri-rhodium complex reveals that the ... [+]
A novel tribenzotriquinacene-based tris-NHC has been obtained and coordinated to rhodium. The new ligand displays a unique rigid C3v symmetry. The electrochemical analysis of the tri-rhodium complex reveals that the three metals are essentially disconnected. [-]
Publicado en
Chemical Communications., 2013, v.49, no. 90Derechos de acceso
© Royal Society of Chemistry 2014
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