Conductivity and Polarization Processes in Highly Cross-Linked Supported Ionic Liquid-Like Phases
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Other documents of the author: García Bernabé, Abel; Compañ, Vicente; Burguete, M. Isabel; Garcia-Verdugo, Eduardo; Karbass, Naima; Luis, Santiago V.; Riande, Evaristo
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Show full item recordcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
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http://dx.doi.org/10.1021/jp910535z |
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Title
Conductivity and Polarization Processes in Highly Cross-Linked Supported Ionic Liquid-Like PhasesAuthor (s)
Date
2010Publisher
American Chemical SocietyISSN
1932-7447Type
info:eu-repo/semantics/articlePublisher version
http://pubs.acs.org/doi/abs/10.1021/jp910535zSubject
Abstract
Supported ionic liquid-like phases were prepared by anchoring imidazolium moieties onto highly cross-linked poly(p-chloromethylstyrene-co-divinylbenzene) monolithic matrixes. The influence of the chemical nature of ... [+]
Supported ionic liquid-like phases were prepared by anchoring imidazolium moieties onto highly cross-linked poly(p-chloromethylstyrene-co-divinylbenzene) monolithic matrixes. The influence of the chemical nature of the anions on the response of supported ionic liquid-like phases to electrical perturbation fields was studied by impedance spectroscopy over wide ranges of frequency and temperature. The exchange of the chloride anions (Cl−) by bis(trifluormethanesulfonyl)amide anions (NTf2−) greatly affects the psychic-chemical properties of the resulting material. The equivalent circuit that describes the impedance response of the SILLP materials used in this study to electrical perturbation fields is a resistance independent of frequency in series with a parallel Rp-CPE circuit. At high frequencies the CPE has the behavior of a capacitance. The ionic conductivity of the system increases 2 orders of magnitude by exchanging Cl− anions for NTf2−. Despite the apparent high cross-linking degree of the supporter, the systems having imidazolium units with Cl− and NTf2− as counterions apparently exhibit a glass−liquid transition in the vicinity of 343 K (70 °C) and 313 K (40 °C), respectively. Dipolar relaxations and conductive process are discussed in terms of chain mobility. [-]
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