Polymer-supported Pd–NHC complexes: Strategies for the development of multifunctional systems
Impacto
Scholar |
Otros documentos de la autoría: Sans, Victor; Gelat, Fabien; Burguete, M. Isabel; Garcia-Verdugo, Eduardo; Luis, Santiago V.
Metadatos
Mostrar el registro completo del ítemcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
comunitat-uji-handle4:
INVESTIGACIONEste recurso está restringido
http://dx.doi.org/10.1016/j.cattod.2012.03.036 |
Metadatos
Título
Polymer-supported Pd–NHC complexes: Strategies for the development of multifunctional systemsAutoría
Fecha de publicación
2012-11Editor
ElsevierISSN
0920-5861Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://www.sciencedirect.com/science/article/pii/S0920586112001964Palabras clave / Materias
Resumen
Different strategies to introduce multiple ionic liquid-like functionalities in PS–DVB based polymers in an easy and reproducible way are reported. A basic common structural element has been, in all cases, the presence ... [+]
Different strategies to introduce multiple ionic liquid-like functionalities in PS–DVB based polymers in an easy and reproducible way are reported. A basic common structural element has been, in all cases, the presence of covalently attached imidazolium subunits able to form palladium–NHC complexes (Pd–NHC) and to stabilize PdNPs. Several structural alternatives have been studied in order to modify the catalytic behavior of the corresponding N-heterocyclic carbenes (NHC) complexes, in terms of both activity and stability. Thus, two types of supported pincer-like ligands were prepared using different linker/spacer combinations. The microenvironment of those supported NHC-ligands was further modified by the introduction of additional IL-like groups based on ammonium, pyridinium and imidazolium moieties. The presence of the additional functionalities in the support proved to play interesting roles in the catalytic activity of the supported catalysts/precatalysts for the Heck Csingle bondC coupling reaction. In particular, catalytic systems derived from resins containing ditopic groups being able to form stable pincer complexes have shown a very remarkable stability with no sign of deactivation after several cycles. [-]
Publicado en
Catalysis Today, 2012, vol. 196, num. 1Derechos de acceso
Copyright © 2012, Elsevier
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/restrictedAccess
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/restrictedAccess
Aparece en las colecciones
- QUIO_Articles [692]