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Tuning the Catalytic Efficiency of Palladium Supported Complexes (Pd-NHC-SILLPs): The Cooperative Effect of the Ionic Liquid-Like Groups
dc.contributor.author | Sans, Victor | |
dc.contributor.author | Gelat, Fabien | |
dc.contributor.author | Burguete, M. Isabel | |
dc.contributor.author | Garcia-Verdugo, Eduardo | |
dc.contributor.author | Luis, Santiago V. | |
dc.date.accessioned | 2013-05-02T07:44:17Z | |
dc.date.available | 2013-05-02T07:44:17Z | |
dc.date.issued | 2012 | |
dc.identifier.issn | 1022-1360 | |
dc.identifier.issn | 1521-3900 | |
dc.identifier.uri | http://hdl.handle.net/10234/62488 | |
dc.description.abstract | Gel-type Supported Ionic Liquid-like Phases (g-SILLPs) have been employed as medium for the preparation of Palladium carbene (Pd-NHC) complexes. These supported complexes onto ionic liquid-like phases were employed as catalysts for the phosphine-, copper- and amine-free Sonogashira reaction showing excellent activity and selectivity. The loading and nature of the ionic liquid-like moieties have proved to have an effect in the reactivity of the different Pd-NHC-g-SILLPs prepared, with TOF values ranging from 450 to 25000 h. | ca_CA |
dc.description.sponsorShip | This work was partially supported by CICYT-MICINN (CTQ2011- 28903) and Bancaixa-UJI (P1 2009-58) grants. | ca_CA |
dc.format.extent | 8 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | WILEY-VCH Verlag | ca_CA |
dc.relation.isPartOf | Macromolecular Symposia (2012), Vol. 317-318 no. 1 | |
dc.rights | Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | Copper-free | ca_CA |
dc.subject | Green chemistry | ca_CA |
dc.subject | Pd | ca_CA |
dc.subject | Sonogashira coupling reaction; | ca_CA |
dc.subject | Supported ionic liquids phases (SILLPs) | ca_CA |
dc.title | Tuning the Catalytic Efficiency of Palladium Supported Complexes (Pd-NHC-SILLPs): The Cooperative Effect of the Ionic Liquid-Like Groups | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1002/masy.201200014 | |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
dc.relation.publisherVersion | http://onlinelibrary.wiley.com/doi/10.1002/masy.201200014/abstract | ca_CA |
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