Tuning the Catalytic Efficiency of Palladium Supported Complexes (Pd-NHC-SILLPs): The Cooperative Effect of the Ionic Liquid-Like Groups
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Scholar |
Otros documentos de la autoría: Sans, Victor; Gelat, Fabien; Burguete, M. Isabel; Garcia-Verdugo, Eduardo; Luis, Santiago V.
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http://dx.doi.org/10.1002/masy.201200014 |
Metadatos
Título
Tuning the Catalytic Efficiency of Palladium Supported Complexes (Pd-NHC-SILLPs): The Cooperative Effect of the Ionic Liquid-Like GroupsAutoría
Fecha de publicación
2012Editor
WILEY-VCH VerlagISSN
1022-1360; 1521-3900Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://onlinelibrary.wiley.com/doi/10.1002/masy.201200014/abstractPalabras clave / Materias
Resumen
Gel-type Supported Ionic Liquid-like Phases (g-SILLPs) have been employed as medium for the preparation of Palladium carbene (Pd-NHC) complexes. These supported complexes onto ionic liquid-like phases were employed ... [+]
Gel-type Supported Ionic Liquid-like Phases (g-SILLPs) have been employed as medium for the preparation of Palladium carbene (Pd-NHC) complexes. These supported complexes onto ionic liquid-like phases were employed as catalysts for the phosphine-, copper- and amine-free Sonogashira reaction showing excellent activity and selectivity. The loading and nature of the ionic liquid-like moieties have proved to have an effect in the reactivity of the different Pd-NHC-g-SILLPs prepared, with TOF values ranging from 450 to 25000 h. [-]
Publicado en
Macromolecular Symposia (2012), Vol. 317-318 no. 1Derechos de acceso
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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