Sulfonate-Functionalized NHC-Based Ruthenium Catalysts for the Isomerization of Allylic Alcohols in Water. Recyclability Studies
comunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
comunitat-uji-handle4:
INVESTIGACIONEste recurso está restringido
http://dx.doi.org/10.1021/om100601r |
Metadatos
Título
Sulfonate-Functionalized NHC-Based Ruthenium Catalysts for the Isomerization of Allylic Alcohols in Water. Recyclability StudiesFecha de publicación
2010Editor
American Chemical SocietyISSN
0276-7333Cita bibliográfica
Organometallics (2010), 29, 16, p. 3661-3664Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://pubs.acs.org/doi/abs/10.1021%2Fom100601rResumen
Two new complexes of the type [Ru(CO3)(η6-arene)(NHC)]Cs, in which the NHC ligand incorporates a sulfonate functionality, have been prepared and fully characterized. The two water-soluble complexes have been tested ... [+]
Two new complexes of the type [Ru(CO3)(η6-arene)(NHC)]Cs, in which the NHC ligand incorporates a sulfonate functionality, have been prepared and fully characterized. The two water-soluble complexes have been tested in the catalytic isomerization of allylic alcohols in water. The p-cymene compound (labeled as 1) was shown to be an excellent catalyst when compared to other related Ru catalysts. This catalyst can be recycled by simple liquid−liquid extractions several times without detected loss of activity. [-]
Derechos de acceso
Copyright © 2010 American Chemical Society
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/closedAccess
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/closedAccess
Aparece en las colecciones
- QUIO_Articles [689]