Sulfonate-Functionalized NHC-Based Ruthenium Catalysts for the Isomerization of Allylic Alcohols in Water. Recyclability Studies
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http://dx.doi.org/10.1021/om100601r |
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Title
Sulfonate-Functionalized NHC-Based Ruthenium Catalysts for the Isomerization of Allylic Alcohols in Water. Recyclability StudiesDate
2010Publisher
American Chemical SocietyISSN
0276-7333Bibliographic citation
Organometallics (2010), 29, 16, p. 3661-3664Type
info:eu-repo/semantics/articlePublisher version
http://pubs.acs.org/doi/abs/10.1021%2Fom100601rAbstract
Two new complexes of the type [Ru(CO3)(η6-arene)(NHC)]Cs, in which the NHC ligand incorporates a sulfonate functionality, have been prepared and fully characterized. The two water-soluble complexes have been tested ... [+]
Two new complexes of the type [Ru(CO3)(η6-arene)(NHC)]Cs, in which the NHC ligand incorporates a sulfonate functionality, have been prepared and fully characterized. The two water-soluble complexes have been tested in the catalytic isomerization of allylic alcohols in water. The p-cymene compound (labeled as 1) was shown to be an excellent catalyst when compared to other related Ru catalysts. This catalyst can be recycled by simple liquid−liquid extractions several times without detected loss of activity. [-]
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- QUIO_Articles [689]