Intramolecular oxidation of the alcohol functionalities in hydroxyalkyl-n-heterocyclic carbene complexes of iridium and rhodium
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Other documents of the author: Benítez Gómez, Miriam; Mas, Elena; Mata Martínez, Jose A; Peris, Eduardo
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Show full item recordcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
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http://dx.doi.org/10.1002/chem.201101187 |
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Title
Intramolecular oxidation of the alcohol functionalities in hydroxyalkyl-n-heterocyclic carbene complexes of iridium and rhodiumDate
2011-08-04Publisher
WILEY-VCH VerlagBibliographic citation
Chemistry - A European Journal (2011), 17, 37, p. 10453–10461Type
info:eu-repo/semantics/articleSubject
Abstract
A series of hydroxyalkyl-functionalized imidazolium salts have been coordinated to Rh and Ir to afford the corresponding MCp*–(NHC) (Cp*=pentamethylcyclopentadienyl) complexes. The reactivity of the new complexes has ... [+]
A series of hydroxyalkyl-functionalized imidazolium salts have been coordinated to Rh and Ir to afford the corresponding MCp*–(NHC) (Cp*=pentamethylcyclopentadienyl) complexes. The reactivity of the new complexes has been studied with special attention to the transformations that deal with the alcohol functionality. The metal-mediated intramolecular transformations allowed the formation of several products that resulted from the oxidation of the alcohols to aldehydes and esters. All the new complexes have been fully characterized, and the crystal structures of the most representative complexes have been resolved. [-]
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