A Y-Shaped tris-N-heterocyclic carbene for the synthesis of simultaneously chelate-monodentate dipalladium complexes
Impacte
Scholar |
Altres documents de l'autoria: Peris, Eduardo; Gonell, Sergio; Mata Martínez, Jose A; Poyatos, Macarena
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Mostra el registre complet de l'elementcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
comunitat-uji-handle4:
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http://dx.doi.org/10.1021/om200820s |
Metadades
Títol
A Y-Shaped tris-N-heterocyclic carbene for the synthesis of simultaneously chelate-monodentate dipalladium complexesData de publicació
2011-11Editor
American Chemical SocietyISSN
0276-7333Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
http://pubs.acs.org/doi/full/10.1021/om200820sParaules clau / Matèries
Resum
A Y-shaped tris-NHC ligand has been obtained and coordinated to palladium, affording metal complexes with novel topological properties. The tris-NHC ligand is capable of coordinating the two metals, affording two ... [+]
A Y-shaped tris-NHC ligand has been obtained and coordinated to palladium, affording metal complexes with novel topological properties. The tris-NHC ligand is capable of coordinating the two metals, affording two different coordination environments. The X-ray molecular structure of two of the complexes are reported. The three new Pd complexes provide good activity in the hydroarylation of alkynes, although we did not find any clear evidence about the benefits of using the dimetallic palladium species in the catalytic outcomes. [-]
Publicat a
Organometallics (Nov. 2011), vol. 30, no. 21, 5985–5990Drets d'accés
© 2011 American Chemical Society
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