A Y-Shaped tris-N-heterocyclic carbene for the synthesis of simultaneously chelate-monodentate dipalladium complexes
Impacto
Scholar |
Otros documentos de la autoría: Peris, Eduardo; Gonell, Sergio; Mata Martínez, Jose A; Poyatos, Macarena
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Metadatos
Título
A Y-Shaped tris-N-heterocyclic carbene for the synthesis of simultaneously chelate-monodentate dipalladium complexesFecha de publicación
2011-11Editor
American Chemical SocietyISSN
0276-7333Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://pubs.acs.org/doi/full/10.1021/om200820sPalabras clave / Materias
Resumen
A Y-shaped tris-NHC ligand has been obtained and coordinated to palladium, affording metal complexes with novel topological properties. The tris-NHC ligand is capable of coordinating the two metals, affording two ... [+]
A Y-shaped tris-NHC ligand has been obtained and coordinated to palladium, affording metal complexes with novel topological properties. The tris-NHC ligand is capable of coordinating the two metals, affording two different coordination environments. The X-ray molecular structure of two of the complexes are reported. The three new Pd complexes provide good activity in the hydroarylation of alkynes, although we did not find any clear evidence about the benefits of using the dimetallic palladium species in the catalytic outcomes. [-]
Publicado en
Organometallics (Nov. 2011), vol. 30, no. 21, 5985–5990Derechos de acceso
© 2011 American Chemical Society
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