Oxidations and Oxidative Couplings Catalyzed by Triazolylidene Ruthenium Complexes
comunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7013
comunitat-uji-handle3:10234/8638
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http://dx.doi.org/10.1021/om101145y |
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Títol
Oxidations and Oxidative Couplings Catalyzed by Triazolylidene Ruthenium ComplexesData de publicació
2011-02-10Editor
American Chemical SocietyCita bibliogràfica
Organometallics 2011 30 (5), 1162-1167Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
http://pubs.acs.org/doi/full/10.1021/om101145yVersió
info:eu-repo/semantics/publishedVersionParaules clau / Matèries
Resum
A series of “RuII(η6-arene)” complexes with 1,2,3-triazolylidene ligands have been prepared and fully characterized. The molecular structure of one of the new complexes has been determined by means of X-ray diffract ... [+]
A series of “RuII(η6-arene)” complexes with 1,2,3-triazolylidene ligands have been prepared and fully characterized. The molecular structure of one of the new complexes has been determined by means of X-ray diffractrometry. The new complexes have been tested in a set of catalytic reactions involving alcohols and amines as substrates, including (i) base-free oxidation of benzylic alcohols to benzaldehydes, (ii) homocoupling of amines to form imines, and (iii) oxidative coupling of amines and alcohols to form amides. The results show the high versatility of the catalysts used and illustrate the application potential of 1,2,3-triazolylidene ligands in the design of effective homogeneous catalysts. [-]
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© 2011 American Chemical Society
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