Oxidations and Oxidative Couplings Catalyzed by Triazolylidene Ruthenium Complexes
comunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7013
comunitat-uji-handle3:10234/8638
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http://dx.doi.org/10.1021/om101145y |
Metadatos
Título
Oxidations and Oxidative Couplings Catalyzed by Triazolylidene Ruthenium ComplexesFecha de publicación
2011-02-10Editor
American Chemical SocietyCita bibliográfica
Organometallics 2011 30 (5), 1162-1167Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://pubs.acs.org/doi/full/10.1021/om101145yVersión
info:eu-repo/semantics/publishedVersionPalabras clave / Materias
Resumen
A series of “RuII(η6-arene)” complexes with 1,2,3-triazolylidene ligands have been prepared and fully characterized. The molecular structure of one of the new complexes has been determined by means of X-ray diffract ... [+]
A series of “RuII(η6-arene)” complexes with 1,2,3-triazolylidene ligands have been prepared and fully characterized. The molecular structure of one of the new complexes has been determined by means of X-ray diffractrometry. The new complexes have been tested in a set of catalytic reactions involving alcohols and amines as substrates, including (i) base-free oxidation of benzylic alcohols to benzaldehydes, (ii) homocoupling of amines to form imines, and (iii) oxidative coupling of amines and alcohols to form amides. The results show the high versatility of the catalysts used and illustrate the application potential of 1,2,3-triazolylidene ligands in the design of effective homogeneous catalysts. [-]
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© 2011 American Chemical Society
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