A redox-switchable catalyst with an 'unplugged' redox tag
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Otros documentos de la autoría: Gutiérrez Peña, Cristian Leonardo; Poyatos, Macarena; Peris, Eduardo
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10.1039/D2CC02497G |
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Título
A redox-switchable catalyst with an 'unplugged' redox tagFecha de publicación
2022-08-24Editor
Royal Society of ChemistryCita bibliográfica
GUTIÉRREZ-PEÑA, Cristian L.; POYATOS, Macarena; PERIS, Eduardo. A redox-switchable catalyst with an ‘unplugged’redox tag. Chemical Communications, 2022, vol. 58, no 75, p. 10564-10567.Tipo de documento
info:eu-repo/semantics/articleVersión
info:eu-repo/semantics/publishedVersionPalabras clave / Materias
Resumen
Two bis-(propyl-imidazolium)-napthalenediimide (NDI) salts were prepared and used as N-heterocyclic carbene (NHC) precursors for the preparation of dimetallic complexes of rhodium and iridium. Infrared spectroelectr ... [+]
Two bis-(propyl-imidazolium)-napthalenediimide (NDI) salts were prepared and used as N-heterocyclic carbene (NHC) precursors for the preparation of dimetallic complexes of rhodium and iridium. Infrared spectroelectrochemical studies indicate that the metals are sensitive to changes in the electronic state of the NDI moiety. The catalytic behavior of the rhodium and iridium complexes was tested in the cycloisomerization of alkynoic acids, where the complexes showed effective redox-switching properties. [-]
Publicado en
Chemical Communications, Volume 58, Issue 75, August 2022Entidad financiadora
Ministerio de Ciencia, Innovación y Universidades (Spain) | Serveis Centrals d’Instrumentació Científica (SCIC-UJI) | Santiago Grisolía Program
Código del proyecto o subvención
PGC2018-093382-B-I00
Derechos de acceso
This journal is © The Royal Society of Chemistry 2022
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