Structural Features of Mono- and Dimetallic Complexes of Palladium Combining Two Types of Aromatic NHC Ligands
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https://doi.org/10.1002/ejic.201900684 |
Metadatos
Título
Structural Features of Mono- and Dimetallic Complexes of Palladium Combining Two Types of Aromatic NHC LigandsFecha de publicación
2019-09-08Editor
ChemPubSoc EuropeISSN
1434-1948Cita bibliográfica
GONELL, Sergio; PERIS, Eduardo; POYATOS, Macarena. Structural Features of Mono‐and Dimetallic Complexes of Palladium Combining Two Types of Aromatic NHC Ligands. European Journal of Inorganic Chemistry, 2019, 2019.33: 3776-3781Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/ejic.201900684Versión
info:eu-repo/semantics/acceptedVersionPalabras clave / Materias
Resumen
A family of palladium complexes that combine two types of aromatic N‐heterocyclic carbene (NHC) ligands has been prepared starting from dinuclear palladium complexes. Two of the complexes are mono‐metallic and contain ... [+]
A family of palladium complexes that combine two types of aromatic N‐heterocyclic carbene (NHC) ligands has been prepared starting from dinuclear palladium complexes. Two of the complexes are mono‐metallic and contain a pyrene‐based mono‐NHC and a benzimidazolylidene ligand. The other two are dimetallic and combine a bridging pyrene‐based bis‐NHC ligand with benzimidazolylidene ligands. All new complexes therefore contain two types of NHC ligands that differ in the size of their aromatic backbones coordinated to the same metal center. All complexes have been characterized and the molecular structure of two of them has been confirmed by X‐ray diffraction studies. [-]
Publicado en
European Journal of Inorganic Chemistry, 2019, 2019.33: 3776-3781Entidad financiadora
Universitat Jaume I
Código del proyecto o subvención
UJI-B2017-07 | UJI-B2018-46
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© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
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