Improving Catalyst Activity in Hydrocarbon Functionalization by Remote Pyrene-Graphene Stacking
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Otros documentos de la autoría: Ballestin, Pilar; Ventura Espinosa, David; Santiago Martín; Martín Solans, Santiago; Caballero, Ana; Mata Martínez, Jose A; Pérez, Pedro J.
Metadatos
Mostrar el registro completo del ítemcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/160292
comunitat-uji-handle3:10234/160293
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INVESTIGACIONMetadatos
Título
Improving Catalyst Activity in Hydrocarbon Functionalization by Remote Pyrene-Graphene StackingAutoría
Fecha de publicación
2019Editor
WileyISSN
0947-6539; 1521-3765Cita bibliográfica
BALLESTIN, Pilar, et al. Improving Catalyst Activity in Hydrocarbon Functionalization by Remote Pyrene‐Graphene Stacking. Chemistry–A European Journal, 2019Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201900964Versión
info:eu-repo/semantics/submittedVersionPalabras clave / Materias
Resumen
A copper complex bearing an N-heterocyclic carbene ligand with a pyrene "tail" attached to the backbone has been prepared and supported on reduced graphene oxide (rGO). The free and supported copper materials have ... [+]
A copper complex bearing an N-heterocyclic carbene ligand with a pyrene "tail" attached to the backbone has been prepared and supported on reduced graphene oxide (rGO). The free and supported copper materials have been employed as homogeneous and heterogeneous catalysts in the functionalization of hydrocarbons such as n-hexane, cyclohexane, and benzene through incorporation of the CHCO2 Et unit from ethyl diazoacetate. The graphene-anchored complex displays higher reaction rates and induces higher yields than its soluble counterpart, features that can be rationalized in terms of a decrease in electron density at the metal center due to a remote net electronic flux from the supported copper complex to the graphene surface. [-]
Descripción
This is the pre-peer reviewed version of the following article: Improving Catalyst Activity in Hydrocarbon Functionalization by Remote Pyrene-Graphene Stacking, which has been published in final form at https://doi. ... [+]
This is the pre-peer reviewed version of the following article: Improving Catalyst Activity in Hydrocarbon Functionalization by Remote Pyrene-Graphene Stacking, which has been published in final form at https://doi.org/10.1002/chem.201900964. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. [-]
Publicado en
Chemistry-A European Journal, 2019Proyecto de investigación
Ministerio de Economía, Industria y Competitividad, Gobierno de España: CTQ2017-82893-C2-1-R;Ministerio de Economía, Industria y Competitividad, Gobierno de España: CTQ2015-69153-C2-2-R; Consejería de Economía, Innovación, Ciencia y Empleo, Junta de Andalucía: P12-FQM-1765Derechos de acceso
© Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/openAccess
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/openAccess
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