A Size‐Flexible Organometallic Box for the Encapsulation of Fullerenes
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Altres documents de l'autoria: Martínez Agramunt, Víctor; Eder, Tobias; Darmandeh, Heidar; Guisado-Barrios, Gregorio; Peris, Eduardo
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comunitat-uji-handle3:10234/160293
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INVESTIGACIONMetadades
Títol
A Size‐Flexible Organometallic Box for the Encapsulation of FullerenesAutoria
Data de publicació
2019-04-19Editor
WileyISSN
1433-7851; 1521-3773Cita bibliogràfica
MARTÍNEZ‐AGRAMUNT, Victor, et al. A size‐flexible organometallic box for the encapsulation of fullerenes. Angewandte Chemie International Edition, 2019, vol. 58, no 17, p. 5682-5686Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201901586Versió
info:eu-repo/semantics/acceptedVersionParaules clau / Matèries
Resum
A palladium‐cornered molecular square with four pyrene‐bis(imidazolylidene) bridging ligands is reported. This metallo‐polygon can encapsulate C60 and C70. The X‐ray diffraction structures of the empty cage as well ... [+]
A palladium‐cornered molecular square with four pyrene‐bis(imidazolylidene) bridging ligands is reported. This metallo‐polygon can encapsulate C60 and C70. The X‐ray diffraction structures of the empty cage as well as the cages complexed with both fullerenes are described. The fullerene encapsulation produces perturbations in the structural parameters of the metallo‐square, showing that it can adjust the shape of its cavity to the size of each fullerene. [-]
Publicat a
Angewandte Chemie International Edition, 2019, vol. 58, no 17Proyecto de investigación
Agencia Estatal de Investigación. Grant Number: IJCI-2015-23407; Universitat Jaume I. Grant Number: UJI-B2017-0Drets d'accés
Copyright © John Wiley & Sons
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info:eu-repo/semantics/openAccess
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info:eu-repo/semantics/openAccess
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