Co2P2O7‐Ni2P2O7 solid solutions: Structural characterization and color
Impacto
Scholar |
Otros documentos de la autoría: Tena, M. A.; Mendoza, Rafael; Trobajo-Fernández, María del Camino; Garcia-Granda, Santiago
Metadatos
Mostrar el registro completo del ítemcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
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https://doi.org/10.1111/jace.16158 |
Metadatos
Título
Co2P2O7‐Ni2P2O7 solid solutions: Structural characterization and colorFecha de publicación
2018-10Editor
Wiley; American Ceramic SocietyCita bibliográfica
ena MÁ, Mendoza R, Trobajo C, García JR, García-Granda S. Co 2 P 2 O 7 – Ni 2 P 2 O 7 solid solutions: Structural characterization and color. J Am Ceram Soc . 2018;00:1 – 10. https://doi.org/10.1111/jace.16158Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
https://onlinelibrary.wiley.com/doi/full/10.1111/jace.16158Versión
info:eu-repo/semantics/publishedVersionPalabras clave / Materias
Resumen
NH4[Co1−yNiyPO4]·H2O (0 ≤ y ≤ 1) single crystals were fired to prepare Co2−xNixP2O7 0 ≤ x ≤ 2 solid solutions between 800 and 1200°C. The structure of these solid solutions is α‐M2P2O7 (M = Co, Ni). The contraction ... [+]
NH4[Co1−yNiyPO4]·H2O (0 ≤ y ≤ 1) single crystals were fired to prepare Co2−xNixP2O7 0 ≤ x ≤ 2 solid solutions between 800 and 1200°C. The structure of these solid solutions is α‐M2P2O7 (M = Co, Ni). The contraction of the unit cell with increasing x confirmed the formation of these solid solutions. The UV–vis–NIR spectra of these solid solutions were consistent with Co(II) and Ni(II) ions in the two different crystallographic sites (octahedral site and square pyramidal site) in the α‐M2P2O7 structure. Due to their thermal stability, Co2−xNixP2O7 (0 ≤ x ≤ 2) solid solutions with α‐M2P2O7 structure can be used as a blue, green, brown or yellow ceramic pigment. [-]
Proyecto de investigación
Ministerio de Ciencia, Innovación y Universidades, Spain (Grant MAT2013‐40950‐R and MAT2016‐78155‐C2‐1‐R)Derechos de acceso
© 2018 The American Ceramic Society
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