Selective hydrosilylation of Alkynes to obtanin vinyl-silanes using a Pt-NHC complex
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Mostra el registre complet de l'elementcomunitat-uji-handle:10234/158176
comunitat-uji-handle2:10234/71345
comunitat-uji-handle3:10234/107363
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Títol
Selective hydrosilylation of Alkynes to obtanin vinyl-silanes using a Pt-NHC complexAutoria
Tutor/Supervisor; Universitat.Departament
Mata Martínez, José Antonio; Universitat Jaume I. Departament de Química Inorgànica i OrgànicaData de publicació
2018-07Editor
Universitat Jaume IResum
The aim of this work is to study the catalytic properties of a platinum molecular
complex and the related hybrid material prepared by immobilization of the
molecular complex onto reduced graphene oxide by non-covalent ... [+]
The aim of this work is to study the catalytic properties of a platinum molecular
complex and the related hybrid material prepared by immobilization of the
molecular complex onto reduced graphene oxide by non-covalent interactions.
This objective can be divided into the following items:
• Synthesis and characterization of an imidazolium salt that would serve as
ligand precursor.
• Synthesis of a new Pt-NHC complex and full characterization by 1H NMR,
APT NMR, COSY, HMBC, HRMS, X-Ray diffraction and TGA
• Immobilization and characterization by TEM and ICP-MS of the Pt-NHC
complex onto rGO
• Study of the catalyst properties of both systems in the hydrosilylation of
alkynes.
• Study of recyclability of the hybrid material in the hydrosilylation of
alkynes.
• Study the mechanism of the hydrosilylation of alkynes reaction [-]
Paraules clau / Matèries
Descripció
Treball Final de Màster Universitari en Química Aplicada i Farmacològica. Codi: SIM138. Curs: 2017/2018
Tipus de document
info:eu-repo/semantics/masterThesisDrets d'accés
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info:eu-repo/semantics/restrictedAccess
info:eu-repo/semantics/restrictedAccess