Thermal Degradation Mechanism of a Thermostable Polyester Stabilized with an Open-Cage Oligomeric Silsesquioxane
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Other documents of the author: Bautista, Yolanda; Gozalbo Nebot, Ana; Mestre Beltrán, Sergio; Sanz-Solana, Vicente
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comunitat-uji-handle2:10234/7033
comunitat-uji-handle3:10234/8618
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Title
Thermal Degradation Mechanism of a Thermostable Polyester Stabilized with an Open-Cage Oligomeric SilsesquioxaneDate
2018Publisher
MDPIISSN
1996-1944Bibliographic citation
Bautista, Y.; Gozalbo, A.; Mestre, S.; Sanz, V. Thermal Degradation Mechanism of a Thermostable Polyester Stabilized with an Open-Cage Oligomeric Silsesquioxane. Materials 2018, 11, 22.Type
info:eu-repo/semantics/articlePublisher version
http://www.mdpi.com/1996-1944/11/1/22Version
info:eu-repo/semantics/publishedVersionSubject
Abstract
A polyester composite was prepared through the polymerization of an unsaturated ester
resin with styrene and an open-cage oligomeric silsesquioxane with methacrylate groups. The effect
of the open-cage oligomeric ... [+]
A polyester composite was prepared through the polymerization of an unsaturated ester
resin with styrene and an open-cage oligomeric silsesquioxane with methacrylate groups. The effect
of the open-cage oligomeric silsesquioxane on the thermal stability of the thermostable polyester
was studied using both thermogravimetric analysis and differential thermal analysis. The results
showed that the methacryl oligomeric silsesquioxane improved the thermal stability of the polyester.
The decomposition mechanism of the polyester/oligomer silsesquioxane composite was proposed by
Fourier transform infrared spectroscopy (FTIR) analysis of the volatiles. [-]
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