Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores

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comunitat-uji-handle:10234/9

comunitat-uji-handle2:10234/7013

comunitat-uji-handle3:10234/8638

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Metadata

Title
Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores
Author (s)
 Petrov, Pavel A.;
 Naumov, Dmitry Yu.;
 Sukhikh, Taisiya S.;
 Konchenko, Sergey N.;
 Gómez García, Carlos J.;
 Llusar, RosaOrcidScopusResearcherIDGoogle Scholar
Date
2017
Publisher
Royal Society of Chemistry
URI
http://hdl.handle.net/10234/170551
DOI
http://doi.org/10.1039/c7nj01217a
ISSN
1144-0546; 1369-9261
Bibliographic citation
New J. Chem., 2017,41, 7849-7852
Type
info:eu-repo/semantics/article
Publisher version
http://pubs.rsc.org/en/content/articlelanding/2017/nj/c7nj01217a#!divAbstract
Version
info:eu-repo/semantics/publishedVersion
Abstract
Electron precise [Mo3(l3-S)(l-S)3(diphos)3Br3]Br (diphos = dppe, dmpe) incomplete cuboidal clusters with six cluster skeletal electrons (CSE) were converted into paramagnetic cuboidal [Mo3(GaBr)(l3-S)4- (diphos)3Br3] ... [+]
Electron precise [Mo3(l3-S)(l-S)3(diphos)3Br3]Br (diphos = dppe, dmpe) incomplete cuboidal clusters with six cluster skeletal electrons (CSE) were converted into paramagnetic cuboidal [Mo3(GaBr)(l3-S)4- (diphos)3Br3] clusters by treatment with elemental Ga. The new heterobimetallic complexes with nine CSE possess a doublet ground state with the unpaired electron density delocalized over the three molybdenum atoms. [-]
Is part of
New J. Chem., 2017, 41
Investigation project
CTQ2015- 65207-P ; PrometeoII/2014/022
Rights
info:eu-repo/semantics/openAccess
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This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017. This article is licensed under a Creative Commons Attribution-NonComercial 4.0 Unported License.
Except where otherwise noted, this item's license is described as This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017. This article is licensed under a Creative Commons Attribution-NonComercial 4.0 Unported License.