Application of optically active chiral bis- (imidazolium) salts as potential receptors of chiral dicarboxylate salts of biological relevance
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Other documents of the author: González, Laura; Escorihuela, Jorge; Altava, Belen; Burguete, M. Isabel; Luis, Santiago V.
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comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
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http://dx.doi.org/10.1039/c5ob00348b |
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Title
Application of optically active chiral bis- (imidazolium) salts as potential receptors of chiral dicarboxylate salts of biological relevanceAuthor (s)
Date
2015Publisher
Royal Society of ChemistryISSN
1477-0520; 1477-0539Bibliographic citation
Org. Biomol. Chem., 2015, 13, 5450Type
info:eu-repo/semantics/articlePublisher version
http://pubs.rsc.org/en/content/articlepdf/2015/ob/c5ob00348bSubject
Abstract
A family of chiral bis(imidazolium) salts derived from natural amino acids has been synthesized by a simple
synthetic approach and the corresponding bis(trifluoromethylsulfonyl)imide salts have been shown to be
room ... [+]
A family of chiral bis(imidazolium) salts derived from natural amino acids has been synthesized by a simple
synthetic approach and the corresponding bis(trifluoromethylsulfonyl)imide salts have been shown to be
room temperature chiral ionic liquids (RTCILs). The structures and self-assembling properties of the
resulting salts have been studied by 1
HNMR, ATR-FTIR, DSC, SEM and theoretical calculations. Moreover,
these receptors have been applied to the enantiomeric recognition of dicarboxylic amino acids.
The supramolecular complexes formed have been studied by 1
HNMR titration experiments, ATR-FTIR
and DSC. [-]
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Org. Biomol. Chem., 2015, 13, 5450–5459Rights
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