Green bioprocesses in sponge-like ionic liquids
Impacto
Scholar |
Otros documentos de la autoría: Lozano, Pedro; Bernal, Juana M.; Gómez, Celia; Garcia-Verdugo, Eduardo; Burguete, M. Isabel; Sánchez Gómez, Gregorio; Vaultier, Michel; Luis, Santiago V.
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Metadatos
Título
Green bioprocesses in sponge-like ionic liquidsAutoría
Fecha de publicación
2015-10-15Editor
ElsevierISSN
0920-5861Cita bibliográfica
LOZANO, Pedro, et al. Green bioprocesses in sponge-like ionic liquids. Catalysis Today, 2015, vol. 255, p. 54-59Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://www.sciencedirect.com/science/article/pii/S0920586114006087Palabras clave / Materias
Resumen
Ionic liquids (ILs) are a new class of liquid solvent, whose use has led to a green chemical revolution because of their unique array of physico-chemical properties, headed by their negligible vapour pressure and their ... [+]
Ionic liquids (ILs) are a new class of liquid solvent, whose use has led to a green chemical revolution because of their unique array of physico-chemical properties, headed by their negligible vapour pressure and their exceptional ability to stabilize biocatalysts. Hydrophobic ILs based on cations with long alkyl side-chains, e.g. N,N,N,N-hexadecyltrimethylammonium bis(trifluoromethylsulfonyl)imide ([C16tma][NTf2]), are temperature switchable ionic liquid/solid phases that behave as sponge-like systems (sponge-like ionic liquid, SLILs). Based on this new property, SLILs have been used to develop straightforward and clean approaches for producing nearly pure synthetic compounds with added value (e.g. geranyl acetate, anisyl acetate, methyl oleate, etc.) in two steps: an enzymatic synthetic step as liquid phase, and then a product separation step involving simple centrifugation as a solid phase. [-]
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Catalysis Today, 2015, vol. 255Derechos de acceso
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