Homoleptic Molybdenum Cluster Sulfides Functionalized with Noninnocent Diimine Ligands: Synthesis, Structure, and Redox Behavior
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Other documents of the author: Gushchin, Artem L.; Laricheva, Yuliya A.; Abramov, Pavel A.; Virovets, Alexander V.; Vicent Barrera, Cristian; Sokolov, Maxim; Llusar, Rosa
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comunitat-uji-handle2:10234/7013
comunitat-uji-handle3:10234/8638
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http://dx.doi.org/10.1002/ejic.201402343 |
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Title
Homoleptic Molybdenum Cluster Sulfides Functionalized with Noninnocent Diimine Ligands: Synthesis, Structure, and Redox BehaviorAuthor (s)
Date
2014Publisher
WileyISSN
1434-1948Type
info:eu-repo/semantics/articlePublisher version
http://onlinelibrary.wiley.com/doi/10.1002/ejic.201402343/abstractVersion
info:eu-repo/semantics/publishedVersionSubject
Abstract
Thiourea (tu) has been coordinated to the Mo3S44+ cluster unit to afford the new cluster compound [Mo3S4(tu)8(H2O)]Cl4·4H2O (1). The high substitutional lability of the thiourea ligands can be exploited to achieve ... [+]
Thiourea (tu) has been coordinated to the Mo3S44+ cluster unit to afford the new cluster compound [Mo3S4(tu)8(H2O)]Cl4·4H2O (1). The high substitutional lability of the thiourea ligands can be exploited to achieve smooth ligand substitution in the Mo3S4 cluster. The reactions of 1 with 1,10-phenanthroline (phen) and 2,2′-bipyridine (bpy) have resulted in new trisubstituted diimino complexes [Mo3S4Cl3L3]+ [L = phen (2), bpy (3)]. The crystal structure of [Mo3S4Cl3(phen)3]Cl·4H2O was determined by X-ray analysis. A solid-state cyclic voltammetry study of 2 shows a ligand-centered reversible two-electron reduction. DFT calculations for [Mo3S4Cl3(phen)3]+ and the 2e-reduced species [Mo3S4Cl3(phen)3]– support our interpretation of the reduction process. Compound 3 undergoes a reversible two-electron reduction, which is more metal-centered on the basis of DFT calculations. [-]
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European Journal of Inorganic Chemistry, 2014, vol. 2014, nº 25, p. 4093-4100Rights
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