Zinc blende versus wurtzite ZnS nanoparticles: control of the phase and optical properties by tetrabutylammonium hydroxide
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Other documents of the author: La Porta, Felipe A.; Andres, Juan; Li, Maximo Siu; Sambrano, Julio; Varela, José A.; Longo, Elson
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comunitat-uji-handle2:10234/7013
comunitat-uji-handle3:10234/8638
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Title
Zinc blende versus wurtzite ZnS nanoparticles: control of the phase and optical properties by tetrabutylammonium hydroxideAuthor (s)
Date
2014Publisher
Royal Society of ChemistryISSN
1463-9076; 1463-9084Bibliographic citation
Phys. Chem. Chem. Phys., 2014, 16, 20127Type
info:eu-repo/semantics/articlePublisher version
http://pubs.rsc.org/en/content/articlepdf/2014/cp/c4cp02611jVersion
info:eu-repo/semantics/acceptedVersioninfo:eu-repo/semantics/acceptedVersion
Abstract
The influence of tetrabutylammonium hydroxide on the phase composition (cubic zinc blende versus
hexagonal wurtzite) of ZnS nanoparticles was studied. The ZnS nanoparticles were prepared by a microwaveassisted
sol ... [+]
The influence of tetrabutylammonium hydroxide on the phase composition (cubic zinc blende versus
hexagonal wurtzite) of ZnS nanoparticles was studied. The ZnS nanoparticles were prepared by a microwaveassisted
solvothermal method, and the phase structure and optical properties along with the growth
process of ZnS nanoparticles were studied. We report XRD, FE-SEM, EDXS, UV-vis and PL measurements,
and first-principles calculations based on TDDFT methods in order to investigate the structural and
electronic properties and the growth mechanism of ZnS nanostructures. The effects as well as the
merits of microwave heating on the process and characteristics of the obtained ZnS nanostructures and
their performance are reported. [-]
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Phys. Chem. Chem. Phys., 2014, 16, 20127--20137Rights
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