A pyrene-based N‑heterocyclic carbene: study of its coordination chemistry and stereoelectronic properties
Impacte
Scholar |
Altres documents de l'autoria: Valdés Rivas, Hugo Christian; Poyatos, Macarena; Peris, Eduardo
Metadades
Mostra el registre complet de l'elementcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
comunitat-uji-handle4:
INVESTIGACIONAquest recurs és restringit
http://dx.doi.org/dx.doi.org/10.1021/om401134w |
Metadades
Títol
A pyrene-based N‑heterocyclic carbene: study of its coordination chemistry and stereoelectronic propertiesData de publicació
2014Editor
American Chemical SocietyISSN
0276-7333; 1520-6041Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
http://bs8lz6ys5q.search.serialssolutions.com/?ctx_ver=Z39.88-2004&ctx_enc=info% ...Resum
A new pyrene-N-heterocyclic carbene ligand has been obtained and coordinated to rhodium and iridium,
affording the corresponding [MCl(NHC)(COD)] and [MCl(NHC)(CO)2] complexes (M = Ir, Rh). The presence of the
pyrene ... [+]
A new pyrene-N-heterocyclic carbene ligand has been obtained and coordinated to rhodium and iridium,
affording the corresponding [MCl(NHC)(COD)] and [MCl(NHC)(CO)2] complexes (M = Ir, Rh). The presence of the
pyrene backbone allows the introduction of a η6
-bonded [RuCp]+ fragment and facilitates the formation of the corresponding
heterometallic complexes of Rh/Ru and Ir/Ru. The stereoelectronic properties of the new ligand have been studied by means of
IR spectroscopy and cyclic voltammetry and demonstrate that the introduction of the [RuCp]+ fragment results in the reduction
of the electron-donating power of the ligand [-]
Publicat a
Organometallics 2014, 33, 394−401Drets d'accés
© 2013 American Chemical Society
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/restrictedAccess
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/restrictedAccess
Apareix a les col.leccions
- QUIO_Articles [690]