• closedAccess   Chemoselective Hydrogenation of Nitroarenes Catalyzed by Molybdenum Sulphide Clusters 

      Pedrajas Gual, Elena; Sorribes, Iván; Gushchin, Artem L.; Laricheva, Yuliya A.; Junge, Henrik; Beller, matthias; Llusar, Rosa Wiley (2017-03-20)
      Herein, we describe an atom efficient and general protocol for the chemoselective hydrogenation of nitroarenes to anilines catalyzed by well-defined diimino and diamino cubane-type Mo3S4 clusters. The novel diimino ...
    • openAccess   Efficient and Selective N‐Methylation of Nitroarenes under Mild Reaction Conditions 

      Pedrajas Gual, Elena; Sorribes, Iván; Guillamón, Eva; Junge, Henrik; Beller, matthias; Llusar, Rosa Wiley (2017)
      Herein, we report a straightforward protocol for the preparation of N,N‐dimethylated amines from readily available nitro starting materials using formic acid as a renewable C1 source and silanes as reducing agents. This ...
    • closedAccess   General and selective iron-catalyzed transfer hydrogenation of nitroarenes without base 

      Llusar, Rosa; Sorribes, Iván; Wienhöfer, Gerrit; Boddien, Albert; Westerhaus, Felix; Junge, Henrik; Junge, Henrik; Beller, matthias American Chemical Society (2011-08)
      The first well-defined iron-based catalyst system for the reduction of nitroarenes to anilines has been developed applying formic acid as reducing agent. A broad range of substrates including other reducible functional ...