Listar por tema "mechanistic studies"
Mostrando ítems 1-4 de 4
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Accessing and Photo-Accelerating Low-Overpotential Pathways for CO2 Reduction: A Bis-Carbene Ruthenium Terpyridine Catalyst
American Chemical Society (2022-10-21)A ruthenium catalyst bearing a bidentate bis(carbene) ligand is prepared and studied as a catalyst for CO2 electroreduction. The catalyst [Ru(tpy)(bis-mim)(MeCN)][PF6]2 (tpy) is 2,2′,:6′,2″-terpyridine; bis-mim is ... -
An Iron Pyridyl-Carbene Electrocatalyst for Low Overpotential CO2 Reduction to CO
American Chemical Society (2021-04-15)Electrocatalysts for CO2 reduction based on first-row transition metal ions have attracted attention as abundant and affordable candidates for energy conversion applications. Yet very few molecular iron electrocatalysts ... -
On the real catalytically active species for CO2 fixation into cyclic carbonates under near ambient conditions: Dissociation equilibrium of [BMIm][Fe(NO)2Cl2] dependant on reaction temperature
Elsevier (2019-05-15)An imidazolium based iron-containing ionic liquid [BMIm][Fe(NO)2Cl2] (BMIm = 1-n-butyl-3-methyl-imidazolium) has been synthesized for the first time and fully characterized employing a wide range of techniques. The iron-based ... -
Rational Design of Simple Organocatalysts for the HSiCl3 Enantioselective Reduction of (E)-N-(1-Phenylethylidene)aniline
MDPI (2021-11-18)Prolinamides are well-known organocatalysts for the HSiCl3 reduction of imines; however, custom design of catalysts is based on trial-and-error experiments. In this work, we have used a combination of computational ...