Listar por tema "mechanism"
Mostrando ítems 1-5 de 5
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A Redox-Switchable Gold(I) Complex for the Hydroamination of Acetylenes: A Convenient Way for Studying Ligand-Derived Electronic Effects
American Chemical Society (2022-03-31)A gold complex with a naphthalene-di-imide-functionalized N-heterocyclic carbene (NHC) ligand was prepared and characterized. The electrochemical studies reveal that the complex is able to undergo two successive reduction ... -
Defect governed zinc-rich columnar AZO thin film and contact interface for enhanced performance of thermocouples
Royal Society of Chemistry (2022-03-01)The research on the stable thermoelectric properties and contact interface of high-precision thin-film thermocouples lags far behind the demand. In this study, a zinc-rich Al-doped ZnO (AZO) thin film was fabricated, in ... -
Kinetics or thermodynamics? Extolling their role to modulate the crystal phases and luminescence of KY3F10:Eu3+ powders
Royal Society of Chemistry (2023-09-28)KY3F10, a fluoride compound with two polymorphs (alpha and delta), has been a subject of study due to its unique properties. Obtaining the metastable delta-phase has been challenging, but this study presents an enhanced ... -
One-pot direct C-H arylation of arenes in water catalysed by RuCl3 center dot nH(2)O-NaOAc in the presence of Zn
Royal Society of Chemistry (2013-06-07)The inexpensive and commercially available catalytic system RuCl3·nH2O–NaOAc–Zn is active in water for the direct C–H arylation of arenes with aryl/heteroaryl chlorides. The reaction can be accelerated by the use of microwave ... -
Redox-Switchable Complexes Based on Nanographene-NHCs
Wiley (2022-05-30)A series of rhodium and iridium complexes with a N-heterocyclic carbene (NHC) ligand decorated with a perylene-diimide-pyrene moiety are described. Electrochemical studies reveal that the complexes can undergo two successive ...