Listar por tema "iridium complexes"
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Carboxylate-Functionalized Mesoionic Carbene Precursors: Decarboxylation, Ruthenium Bonding, and Catalytic Activity in Hydrogen Transfer Reactions
American Chemical Society (2016)Metalation of a carboxylate-functionalized pyridyl-triazolium salt containing a N1-bound pyridyl substituent either by direct means with [RuCl2(cymene)]2 or via a transmetalation procedure involving Ag2O and [RuCl2(cymene)]2 ... -
Key factors in pincer ligand design
Royal Society of Chemistry (2018)Pincers, tridentate ligands that prefer a meridional geometry, are a rising class because of their distinctive combination of properties. They permit a good level of control on the nature of the coordination sphere by ... -
Unveiling the stereoelectronic properties of a triphenylene-based tris N-heterocyclic carbene
Royal Society of Chemistry (2013-06-14)Two rhodium complexes with a triphenylene-based tris-NHC have been fully characterized. DFT and electrochemical studies suggest that the electronic communication between the metals is very weak, and that the electron ...