Listar por tema "Rodi"
Mostrando ítems 1-2 de 2
-
Double CH bond activation of C(sp3)H2 groups for the preparation of complexes with back-to-back bisimidazolinylidenes
Wiley (2011-06-29)Two-headed carbenes: N-heterocyclic carbene complexes of rhodium and iridium were obtained by the double CH activation of CH2 groups in N heterocycles (see structure: C gray, N blue, Cl green, Ir pink). The reaction ... -
Intramolecular oxidation of the alcohol functionalities in hydroxyalkyl-n-heterocyclic carbene complexes of iridium and rhodium
WILEY-VCH Verlag (2011-08-04)A series of hydroxyalkyl-functionalized imidazolium salts have been coordinated to Rh and Ir to afford the corresponding MCp*–(NHC) (Cp*=pentamethylcyclopentadienyl) complexes. The reactivity of the new complexes has been ...