Listar por tema "Chlorine compounds"
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Chiral palladacycles with N‑heterocyclic carbene ligands as catalysts for asymmetric hydrophosphination
American Chemical Society (2013)Design of chiral palladacycles with N-heterocyclic carbene (NHC) ligands has been carried out in good yields starting form commercially available enantiopure benzylamines. The methodology developed consists of the formation ... -
Conductivity and Polarization Processes in Highly Cross-Linked Supported Ionic Liquid-Like Phases
American Chemical Society (2010)Supported ionic liquid-like phases were prepared by anchoring imidazolium moieties onto highly cross-linked poly(p-chloromethylstyrene-co-divinylbenzene) monolithic matrixes. The influence of the chemical nature of the ... -
Coordination singularities of a bis(p-xylyl)bis(benzimidazolylidene) ligand and the bis-iridium and -rhodium-related complexes
American Chemical Society (2013)The reaction of bis(α,α′-p-xylyl)bis(benzimidazolium) dichloride with [IrCpCl2]2 or [RhCl(COD)]2 affords the corresponding dimetallic bis-N-heterocyclic carbene complexes of Ir and Rh. The reaction with the iridium complex ... -
Protein Ion Channels as Molecular Ratchets. Switchable Current Modulation in Outer Membrane Protein F Porin Induced by Millimolar La3+ Ions
American Chemical Society (2012)The quest for innovative tunable nanodevices has mainly focused on switches that modulate their properties through engineered conformational changes. We propose here an alternative route that takes advantage of the crucial ... -
Synthesis and optical power limiting properties of heteroleptic Mo3S7 clusters
Royal Society of Chemistry (2015)Substitution of the halide ligands in (Bu4N)2[Mo3S7X6] (X = Cl, Br) by diimine ligands, such as 4,4′-dimethyl-2,2′-bipyridine (dmbpy), 2,2′-bipyridine (bpy) and 1,10-phenanthroline (phen), affords the neutral heteroleptic ...