Browsing by Author "ddf2178f-31a9-4126-a999-262ace589db5"
Now showing items 1-11 of 11
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A resorcinarene-based tetrabenzoimidazolylidene complex of rhodium
Ruiz-Botella, Sheila; Vidossich, Pietro; Ujaque, Gregori; Peris, Eduardo Royal Society of Chemistry (2020-03-14)A tetrabenzoimidazolium-resorcinarene cavitand was used for the preparation of a tetra-benzoimidazolylidene of rhodium, which is unprecedented in the field of poly-NHC metal complexes. Both, the experimental and computational ... -
A Tetraferrocenyl-Resorcinarene Cavitand as a Redox-Switchable Host of Ammonium Salts
Ruiz-Botella, Sheila; Vidossich, Pietro; Ujaque, Gregori; Vicent Barrera, Cristian; Peris, Eduardo Wiley (2015-06-10)Tetraannulation of a resorcinarene-octaamino cavitand with ferrocenecarboxaldehyde allows the preparation of a tetrabenzimidazole-resorcinarene cavitand with four ferrocenyl moieties directly linked to the C2 atom of the ... -
Coordination singularities of a bis(p-xylyl)bis(benzimidazolylidene) ligand and the bis-iridium and -rhodium-related complexes
Ruiz-Botella, Sheila; Guisado-Barrios, Gregorio; Mata Martínez, Jose A; Peris, Eduardo American Chemical Society (2013)The reaction of bis(α,α′-p-xylyl)bis(benzimidazolium) dichloride with [IrCpCl2]2 or [RhCl(COD)]2 affords the corresponding dimetallic bis-N-heterocyclic carbene complexes of Ir and Rh. The reaction with the iridium complex ... -
Immobilization of pyrene - adorned N - heterocyclic carbene complexes of rhodium (I) on reduced graphene oxide and study of catalytic activity
Ruiz-Botella, Sheila; Peris, Eduardo Wiley (2018-04-24)Twopyrene-tagged N-heterocyclic carbene (NHC) complexes of rhodium(I) wereobtained and characterized. Thetwo complexes were supported onto reduced graphene oxide (rGO), generating two new materials in which the molecular ... -
Micro-scale Experiments in the Increasingly Fashionable Laboratory in High Schools
Ruiz-Botella, Sheila; Ibáñez, Susana Science Publishing Group (2020)Objective: Experimental activities in laboratories are an important part in teaching and learning chemistry. Nevertheless, its implementation may be limited by the lack of material, instrument and above all the risk ... -
Nickel-Cornered Molecular Rectangles as Polycyclic Aromatic Hydrocarbon Receptors
Martínez Agramunt, Víctor; Ruiz-Botella, Sheila; Peris, Eduardo Wiley (2017)Two nickel-cornered organometallic metalla-rectangles containing a pyrene-linked-di-N-heterocyclic carbene have been prepared. The dimensions of one side of the rectangle were modulated by either using pyrazine or ... -
Phenylene- and biphenylene-bridged bis-imidazolylidenes of palladium. Influence of the presence of pyrene tags on the catalytic activity of the complexes
Ruiz-Botella, Sheila; Peris, Eduardo American Chemical Society (2014)A series of dimetallic complexes with N-heterocyclic carbene ligands with formally identical stereoelectronic properties have been obtained and fully characterized. The dimetallic complexes were bridged by bis-imidazolylidenes, ... -
Programación didáctica sintética 4º ESO Física y Química
Ruiz-Botella, Sheila Universitat Jaume I (2018-06-26)El presente documento es un trabajo de final de Máster de Profesorado de Educación Secundaría obligatoria y Formación profesional. El trabajo se enmarca dentro de la modalidad de Programación Didáctica, por lo que se ... -
Rim, Side Arms, and Cavity: Three Sites for the Recognition of Anions by Tetraazolium Resorcinarene Cavitands
Ruiz-Botella, Sheila; Vidossich, Pietro; Ujaque, Gregori; Peris, Eduardo Wiley (2016-09)Two tetrabenzoimidazolium-resorcinarene cavitands were prepared and used for the recognition of chloride, bromide, iodide, cyanide, nitrate, perchlorate, hexanoate, benzenesulfonate, and p-toluenesulfonate. Binding affinities ... -
Tripodal halogen bonding iodo-azolium receptors for anion recognition
Ruiz-Botella, Sheila; Vidossich, Pietro; Ujaque, Gregori; Peris, Eduardo; Beer, Paul D. Royal Society of Chemistry (2017)The synthesis, characterization and anion binding properties of 1,3,5-tri-substituted benzene platform-based tripodal receptors containing halogen bonding (XB) iodo-imidazolium and iodo-triazolium motifs, and hydrogen ... -
Unveiling the Importance of π-Stacking in Borrowing-Hydrogen Processes Catalysed by Iridium Complexes with Pyrene Tags
Ruiz-Botella, Sheila; Peris, Eduardo Wiley (2015-09-10)This work describes the preparation of a series of pyrene-tagged N-heterocyclic carbene complexes of iridium, and their use in two benchmark borrowing hydrogen reactions: the reduction of ketones by transfer hydrogenation ...