Listar por autoría "cca808e5-3b63-4779-933a-4e42c45e4108"
Mostrando ítems 1-9 de 9
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A palladium-hinged organometallic square with a perfect-sized cavity for the encapsulation of three heteroguests
Martínez Agramunt, Víctor; Peris, Eduardo Royal Society of Chemistry (2019-12-25)A nanometer-sized tetrapalladium metallosquare with a pyrene-bisimidazolylidene ligand was found to display a perfect-sized cavity for the encapsulation of three heteroguests, enabling the formation of quintuple D–A–D–A–D ... -
A Shape‐Adaptable Organometallic Supramolecular Coordination Cage for the Encapsulation of Fullerenes
Martínez Agramunt, Víctor; Gusev, Dmitry; Peris, Eduardo Wiley (2018-10-01)The development of three‐dimensional supramolecular coordination complexes (SCCs), with cavities suitable for guest binding, is of great interest because these materials are useful in a large number of applications. Herein, ... -
A Size‐Flexible Organometallic Box for the Encapsulation of Fullerenes
Martínez Agramunt, Víctor; Eder, Tobias; Darmandeh, Heidar; Guisado-Barrios, Gregorio; Peris, Eduardo Wiley (2019-04-19)A palladium‐cornered molecular square with four pyrene‐bis(imidazolylidene) bridging ligands is reported. This metallo‐polygon can encapsulate C60 and C70. The X‐ray diffraction structures of the empty cage as well as the ... -
A Sustainable Approach to Selective Hydrogenation of Unsaturated Esters and Aldehydes with Ruthenium Catalysts
Passos, Lucas H. R.; Martínez Agramunt, Víctor; Gusev, Dmitry; Peris, Eduardo; dos Santos, Eduardo Wiley (2023-05-12)The reduction of esters and aldehydes to alcohols is an important reaction in the chemical industry to produce a wide range of bulk and fine chemicals. Herein, the unexpected behavior of three state-of-the-art, commercially ... -
Ion Mobility Mass Spectrometry Uncovers Guest-Induced Distortions in a Supramolecular Organometallic Metallosquare
Vicent Barrera, Cristian; Martínez Agramunt, Víctor; Gandhi, Viraj; Larriba, Carlos; Gusev, Dmitry; Peris, Eduardo Wiley (2021)The encapsulation of the tetracationic palladiummetallosquare with four pyrene-bis-imidazolylidene ligands[1]4+with aseries of organic molecules was studied byElectrosprayionization Travelling Wave Ion-Mobility MassSpectrometry ... -
Nickel-Cornered Molecular Rectangles as Polycyclic Aromatic Hydrocarbon Receptors
Martínez Agramunt, Víctor; Ruiz-Botella, Sheila; Peris, Eduardo Wiley (2017)Two nickel-cornered organometallic metalla-rectangles containing a pyrene-linked-di-N-heterocyclic carbene have been prepared. The dimensions of one side of the rectangle were modulated by either using pyrazine or ... -
Novel Family of Nickel (II)-Cornered Molecular Cages with Bis-NHC Bridging Groups
Martínez Agramunt, Víctor Universitat Jaume I (2016-07-21)Metal-directed self-assembly has been widely studied in the last decades since Lehn and co-workers demonstrate the spontaneous self-assembly of dinuclear helicates from 2,2’-bipyridine and copper(I). Thereafter, a ... -
Photocatalytic Properties of a Palladium Metallosquare with Encapsulated Fullerenes via Singlet Oxygen Generation
Martínez Agramunt, Víctor; Peris, Eduardo American Chemical Society (2019-08-12)Singlet oxygen has recently attracted a great deal of attention due to its strong oxidizing properties, which makes it useful in organic synthesis and biological studies. However, the photosensitizers that are required for ... -
Synthesis of tri-pyridinium and bis-imidazolium salts for the preparation of the related N-Heterocyclic carbene Au(I) complexes
Martínez Agramunt, Víctor Universitat Jaume I (2014)The main purpose of this research project is to develop new multimetallic complexes, and to explore the relationship between the structural features and the catalytic behavior. This general aim can be divided into ...