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Synthesis, molecular and electronic structure of an incomplete cuboidal Re3S4 cluster with an anusual quadruplet ground state
Llusar, Rosa; Petrov, Pavel A.; Virovets, Alexander V.; Bogomyakov, Artem S.; Gómez García, Carlos J.; Polo Ortiz, Victoriano; Konchenko, Sergey N. The Royal Society of Chemistry (2012-01)A Re(IV) cluster complex [Re3(μ3-S)(μ-S)3(dppe)3Br3]+ with nine cluster skeletal electrons (CSE) and a quadruplet ground state has been prepared by treatment of [Re3S7Br6]Br with 1,2-bis(diphenylphosphino)ethane (dppe) in MeCN.