Browsing by Author "6c84dd4a-7aa2-4e6d-b565-95a71b13522a"

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    • closedAccess   Dithiolene dimetallic molybdenum(V) complexes displaying intraligand charge transfer (ILCT) emission 

      Recatalá Ferrandis, David; Gushchin, Artem L.; Llusar, Rosa; Galindo, Francisco; Brylev, Konstantin A.; Ryzhikov, Maxim R.; Kitamura, Noboru Royal Society of Chemistry (2013)
      Bifunctional dithiolene ligands have been coordinated to the MoV(O)(μ-S2)MoV(O) unit to afford [Mo2O2(μ-S)2(BPyDTS2)2]2− (12−) (BPyDTS2 (2-bis-(2-pyridyl)methylene-1,3-dithiolene) dianions. Reaction of the 12− molybdenum ...

    • closedAccess   First heteroleptic Mo3S7 clusters containing non-innocent phenanthroline ligands 

      Llusar, Rosa; Recatalá Ferrandis, David; Gushchin, Artem L.; Abramov, Pavel A. SP MAIK Nauka/Interperiodica (2012-03)
      Reaction of the thiobromide [Mo3S7Br6]2− cluster anion with 5,6-dimethyl-1,10-phenanthroline (Me2Phen) in solution leads to the substitution of two bromide ligands and the subsequent formation of a new mixed-ligand neutral ...

    • closedAccess   Heteroleptic Phenanthroline Complexes of Trinuclear Molybdenum Clusters with Luminescent Properties 

      Recatalá Ferrandis, David; Llusar, Rosa; Galindo, Francisco; Brylev, Konstantin A.; Gushchin, Artem L. Wiley (2015)
      Neutral Mo3(μ3-S)(μ-S2)3X3(diimine) (X = Cl–, Br–) heteroleptic cluster complexes containing the 1,10-phenanthroline ligands 1H-imidazo[4,5-f][1,10]phenanthroline-2-[3,4-bis(dodecyloxy)phenyl] (IPDOP), 4,7-diphenyl-1,10- ...

    • closedAccess   Photogeneration of Hydrogen from Water by Hybrid Molybdenum Sulfide Clusters Immobilized on Titania 

      Recatalá Ferrandis, David; Llusar, Rosa; Gushchin, Artem L.; Kozlova, Ekaterina A.; Laricheva, Yuliya A.; Abramov, Pavel A.; Sokolov, Maxim; Gómez, Roberto; Lana-Villarreal, Teresa John Wiley & Sons (2015)
      Two new hybrid molybdenum(IV) Mo3S7 cluster complexes derivatized with diimino ligands have been prepared by replacement of the two bromine atoms of [Mo3S7Br6]2− by a substituted bipyridine ligand to afford heteroleptic ...

    • openAccess   Synthesis and optical power limiting properties of heteroleptic Mo3S7 clusters 

      Recatalá Ferrandis, David; Llusar, Rosa; Barlow, Adam; Wang, Genmiao; Samoc, Marek; Humphrey, Mark G.; Gushchin, Artem L. Royal Society of Chemistry (2015)
      Substitution of the halide ligands in (Bu4N)2[Mo3S7X6] (X = Cl, Br) by diimine ligands, such as 4,4′-dimethyl-2,2′-bipyridine (dmbpy), 2,2′-bipyridine (bpy) and 1,10-phenanthroline (phen), affords the neutral heteroleptic ...