Listar por autoría "0b8fdd37-8101-409c-9b0e-ebc4c270206a"
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Halogen bonding interactions with the [Mo3S7Cl6]2-cluster anion in the mixed valence salt [EDT-TTFI2]4[Mo3S7Cl6]oCH3CN
Alberola Catalán, Antonio; Fourmigué, Marc; Gómez García, Carlos J.; Llusar, Rosa; Triguero Bascuñán, Sonia Royal Society of Chemistry (2008)Electrocrystallization of iodinated TTF molecules in presence of trinuclear [Mo3S7Cl6]2- cluster anions provides the first example of radical salts with halogen bonding interactions at the organic/inorganic interface -
Mo3Q7 (Q = S, Se) Clusters Containing Dithiolate/Diselenolate Ligands: Synthesis, Structures, and Their Use as Precursors of Magnetic Single-Component Molecular Conductors
Gushchin, Artem L.; Llusar, Rosa; Vicent Barrera, Cristian; Abramov, Pavel A.; Gómez García, Carlos J. WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim (2013-05)The coordination chemistry of dithiolene and diselenolene ligands towards the all-selenium [Mo3Se7Br6]2– dianion has been investigated. Complexes (nBu4N)2[Zn(dmit)2] (dmit = 1,3-dithia-2-thioxo-4,5-dithiolate) and ... -
Synthesis and Molecular and Electronic Structures of a Series of Mo3CoSe4 Cluster Complexes with Three Different Metal Electron Populations
Alberola Catalán, Antonio; Llusar, Rosa; Vicent Barrera, Cristian; Andres, Juan; Polo Ortiz, Victoriano; Gómez García, Carlos J. American Chemical Society (2008-03)The synthesis, crystal structure, and magnetic properties of [Mo3(CoCO)Se4(dmpe)3Cl3] (1), [Mo3(CoCl)Se4(dmpe)3Cl3] (2), and [Mo3(CoCl)Se4(dmpe)3Cl3](TCNQ) ([2](TCNQ)) (dmpe = 1,2-bis(dimethylphosphanyl)ethane; TCNQ = ... -
Synthesis and structure of a paramagnetic Mo3S4 incomplete cuboidal cluster with seven cluster skeletal electrons
Petrov, Pavel A.; Naumov, Dmitry Yu; Llusar, Rosa; Gómez García, Carlos J.; Polo Ortiz, Victoriano; Konchenko, Sergey N. Royal Society of Chemistry (2012-08)The electron precise incomplete cuboidal complex [Mo3S4(dppe)3Br3]Br (1a) with 6 cluster skeletal electrons (CSE) and its halogen-mixed analogue [Mo3S4(dppe)3(Br,Cl)3](Br,Cl) (1b) can be smoothly reduced to the paramagnetic ... -
Synthesis, molecular and electronic structure of an incomplete cuboidal Re3S4 cluster with an anusual quadruplet ground state
Llusar, Rosa; Petrov, Pavel A.; Virovets, Alexander V.; Bogomyakov, Artem S.; Gómez García, Carlos J.; Polo Ortiz, Victoriano; Konchenko, Sergey N. The Royal Society of Chemistry (2012-01)A Re(IV) cluster complex [Re3(μ3-S)(μ-S)3(dppe)3Br3]+ with nine cluster skeletal electrons (CSE) and a quadruplet ground state has been prepared by treatment of [Re3S7Br6]Br with 1,2-bis(diphenylphosphino)ethane (dppe) in MeCN. -
Synthesis, molecular and electronic structures of a paramagnetic trimetallic cluster containing an unusual Mo3(l3-Se)2(l-Se)3 core
Petrov, Pavel A.; Ryzhikov, Maxim R.; Virovets, Alexander V.; Konchenko, Sergey N.; Gómez García, Carlos J.; Llusar, Rosa Elsevier (2014)The electron precise [Mo3(l3-Se)(l-Se)3(dppe)3Br3] + incomplete cuboidal complex, with six cluster skeletal electrons (CSE), was converted into the paramagnetic bicapped [Mo3(l3-Se)2(l-Se)3(dppe)3] + cluster (1+ ), ... -
Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores
Petrov, Pavel A.; Naumov, Dmitry Yu.; Sukhikh, Taisiya S.; Konchenko, Sergey N.; Gómez García, Carlos J.; Llusar, Rosa Royal Society of Chemistry (2017)Electron precise [Mo3(l3-S)(l-S)3(diphos)3Br3]Br (diphos = dppe, dmpe) incomplete cuboidal clusters with six cluster skeletal electrons (CSE) were converted into paramagnetic cuboidal [Mo3(GaBr)(l3-S)4- (diphos)3Br3] ... -
Trinuclear Mo3S7 Clusters Coordinated to Dithiolate or Diselenolate Ligands and Their Use in the Preparation of Magnetic Single Component Molecular Conductors
Llusar, Rosa; Triguero Bascuñán, Sonia; Polo Ortiz, Victoriano; Vicent Barrera, Cristian; Gómez García, Carlos J.; Jeannin, Olivier; Fourmigué, Marc American Chemical Society (2008-09)A general route for the preparation of a series of dianionic Mo3S7 cluster complexes bearing dithiolate or diselenolate ligands, namely, [Mo3S7L3]2− (where L = tfd (bis(trifluoromethyl)-1,2-dithiolate) (42−), bdt ...