Listar por autoría "fce5afbe-0afe-4181-9b82-701819eaad08"
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Accessing and Photo-Accelerating Low-Overpotential Pathways for CO2 Reduction: A Bis-Carbene Ruthenium Terpyridine Catalyst
Assaf, Eric A.; Gonell, Sergio; Chen, Chun-Hsing; Miller, Alexander American Chemical Society (2022-10-21)A ruthenium catalyst bearing a bidentate bis(carbene) ligand is prepared and studied as a catalyst for CO2 electroreduction. The catalyst [Ru(tpy)(bis-mim)(MeCN)][PF6]2 (tpy) is 2,2′,:6′,2″-terpyridine; bis-mim is ... -
An Iron Bis(carbene) Catalyst for Low Overpotential CO2 Electroreduction to CO: Mechanistic Insights from Kinetic Zone Diagrams, Spectroscopy, and Theory
Gonell, Sergio; Assaf, Eric A.; Lloret Fillol, Julio; Miller, Alexander American Chemical Society (2021-12-08)A common challenge in molecular electrocatalysis is the relationship between maximum activity and the overpotential required to reach that rate, with faster catalysts incurring higher overpotentials. This work follows a ...