Listar por autoría "96af8c40-60a4-4efe-8846-32faed85cc88"
Mostrando ítems 1-19 de 19
-
A Perovskite Photovoltaic Mini-Module-CsPbBr3 Photoelectrochemical Cell Tandem Device for Solar-Driven Degradation of Organic Compounds
Lee, Seul-Yi; Serafini, Patricio; Masi, Sofia; Gualdrón Reyes, Andrés Fabián; Mesa, Camilo A.; Rodriguez-Pereira, Jhonatan; Gimenez, Sixto; Lee, Hyo Joong; Mora-Sero, Ivan American Chemical Society (2023-10-02)Recently, halide perovskites have been widely explored for high-efficiency photocatalysis or photoelectrochemical (PEC) cells. Here, in order to make an efficient photoanode electrode for the degradation of pollutants, ... -
Application of Halide Perovskite Nanocrystals in Solar-Driven Photo(electro)Catalysis
Gualdrón Reyes, Andrés Fabián; Mesa, Camilo A.; Gimenez, Sixto; Mora-Sero, Ivan Wiley (2022-03-15)Photo(electro)catalysis (PEC) is a promising strategy to conduct attractive solar-driven reactions such as CO2 reduction to form added-value products, H2 production, and organic substrates oxidation, taking advantage of ... -
Direct Observation of the Chemical Transformations in BiVO4 Photoanodes upon Prolonged Light-Aging Treatments
Arcas, Ramón; Cardenas-Morcoso, Drialys; Spadaro, Maria Chiara; García-Tecedor, Miguel; Mesa, Camilo A.; Arbiol, Jordi; Fabregat-Santiago, Francisco; Gimenez, Sixto; Mas, Elena Wiley (2022-03-11)Exposing BiVO4 photoanodes to light-aging treatments is known to produce a significant photocurrent enhancement. Until now, the interpretation given to this phenomenon is associated to the formation of oxygen vacancies and ... -
Efficient and Stable Blue- and Red-Emitting Perovskite Nanocrystals through Defect Engineering: PbX2 Purification
Lee, ChaeHyun; Shin, YeJi; Villanueva Antoli, Alexis; Das Adhikari, Samrat; Rodriguez-Pereira, Jhonatan; Macak, Jan; Mesa, Camilo A.; Gimenez, Sixto; YOON, SEOG JOON; Gualdrón Reyes, Andrés Fabián; Mora-Sero, Ivan American Chemical Society (2021-11-11)Current efforts to reduce the density of structural defects such as surface passivation, doping, and modified synthetic protocols have allowed us to grow high-quality perovskite nanocrystals (PNCs). However, the role of ... -
Efficient Ligand Passivation Enables Ultrastable CsPbX3 Perovskite Nanocrystals in Fully Alcohol Environments
Gualdrón Reyes, Andrés Fabián; Fernandez-Climent, Roser; Masi, Sofia; Mesa, Camilo A.; Echeverría-Arrondo, Carlos; Aiello, Federica; Balzano, Federica; Uccello-Barretta, Gloria; Rodríguez-Pereira, Jhonatan; Gimenez, Sixto; Mora-Sero, Ivan Wiley (2023)Halide perovskite nanocrystals (PNCs) have demonstrated their wide potential to fabricate efficient optoelectronic devices and to prepare promising photocatalysts for solar-driven photo(electro)chemical reactions. However, ... -
Facile Surfactant-Assisted Synthesis of BiVO4 Nanoparticulate Films for Solar Water Splitting
Montañés, Laura; Mesa, Camilo A.; Gutiérrez-Blanco, Ana; Robles, Christian; Julian-Lopez, Beatriz; Gimenez, Sixto MDPI (2021-10-15)Bismuth vanadate (BiVO4), which has attractive applicability as a photoactive material, presents applications that range from catalysis to water treatment upon visible light irradiation. In this study, we develop a simple ... -
Highly Durable Nanoporous Cu2–xS Films for Efficient Hydrogen Evolution Electrocatalysis under Mild pH Conditions
Fernandez-Climent, Roser; Redondo, Jesús; García-Tecedor, Miguel; Spadaro, Maria Chiara; Li, Junnan; Chartrand, Daniel; Schiller, Frederik; Pazos, Jhon; Hurtado, Mikel F.; de la Peña O'Shea, Víctor Antonio; Kornienko, Nikolay; Arbiol, Jordi; Barja, Sara; Mesa, Camilo A.; Gimenez, Sixto American Chemical Society (2023-08-04)Copper-based hydrogen evolution electrocatalysts are promising materials to scale-up hydrogen production due to their reported high current densities; however, electrode durability remains a challenge. Here, we report a ... -
Impact of Oxygen Vacancy Occupancy on Charge Carrier Dynamics in BiVO4 Photoanodes
Selim, Shababa; Pastor , Ernest; García-Tecedor, Miguel; Morris, Madeleine; Francàs Forcada, Laia; Sachs, Michael; Moss, Benjamin; Corby, Sacha; Mesa, Camilo A.; Gimenez, Sixto; Kafizas, Andreas; Bakulin, Artem; Durrant, James American Chemical Society (2019-11-27)Oxygen vacancies are ubiquitous in metal oxides and critical to performance, yet the impact of these states upon charge carrier dynamics important for photoelectrochemical and photocatalytic applications remains contentious ... -
Improved Photoelectrochemical Performance of WO3/BiVO4 Heterojunction Photoanodes via WO3 Nanostructuring
Nomellini, Chiara; Polo, Annalisa; Mesa, Camilo A.; Pastor , Ernest; Marra, Gianluigi; Grigioni, Ivan; Dozzi, Maria Vittoria; Gimenez, Sixto; Selli, Elena American Chemical Society (2023-11-15)WO3/BiVO4 heterojunction photoanodes can be efficiently employed in photoelectrochemical (PEC) cells for the conversion of water into molecular oxygen, the kinetic bottleneck of water splitting. Composite WO3/BiVO4 ... -
Photoelectrochemical water splitting with dual-photoelectrode tandem and parallel configurations: Enhancing light harvesting and carrier collection efficiencies
Keshavarzi, Reza; Mousavian, Mahlasadat; Omrani, MirKazem; Mirkhani, Valiollah; Afzali, Niloufar; Mesa, Camilo A.; Mohammadpoor-Baltork, Iraj; Gimenez, Sixto Elsevier (2023)Photoelectrochemical (PEC) water splitting stands out as one of the most promising technologies to store solar energy into chemical bonds and decarbonize industry and transport. In the present study, we develop ... -
Rational Design of Carbon Nitride Photoelectrodes with High Activity Toward Organic Oxidations
Pulignani, Carolina; Mesa, Camilo A.; Hillman, Sam; Uekert, Taylor; Gimenez, Sixto; Durrant, James R.; Reisner, Erwin Wiley (2022-12-12)Carbon nitride (CNx) is a light-absorber with excellent performance in photocatalytic suspension systems, but the activity of CNx photoelectrodes has remained low. Here, cyanamide-functionalized CNx (NCNCNx) was co-deposited ... -
Role of Pd in the Electrochemical Hydrogenation of Nitrobenzene Using CuPd Electrodes
Carvajal, David; Arcas, Ramón; Mesa, Camilo A.; Fabregat-Santiago, Francisco; Mas, Elena Wiley (2022-04)Interest in the electrochemical reduction of organic compounds as an alternative to hydrogen electrosynthesis is driven, among other reasons, by the fact that the products obtained in this process may have more economic ... -
Ru-based nanoparticles supported on carbon nanotubes for electrocatalytic hydrogen evolution: structural and electronic effects
Romero, Núria; Fenoll, Dídac A.; Gil Jiménez, Laia; Campos Jara, Sergi; Creus, Jordi; Martí Balaguer, Gerard; Heras-Domingo, Javier; Collière, Vincent; Mesa, Camilo A.; Gimenez, Sixto; Francàs Forcada, Laia; Rodriguez-Santiago, Luís; Solans Monfort, Xavier; Sodupe, Mariona; Bofill, Roger; PHILIPPOT, Karine; García-Antón, Jordi; Sala, Xavier Royal Society of Chemistry (2023-10-10)The performance of Ru-based nanoparticles (NPs) in the hydrogen evolution reaction (HER) relies on both their structural properties and the oxidation state of the metal. Herein, the versatility of the organometallic approach ... -
Separating bulk and surface processes in NiOx electrocatalysts for water oxidation
Corby, Sacha; García-Tecedor, Miguel; Tengeler, Sven; Steinert, Céline; Moss, Benjamin; Mesa, Camilo A.; Heiba, Hany Fathy; Wilson, Anna A.; Kaiser, Bernhard; Jaegermann, Wolfram; Francàs Forcada, Laia; Gimenez, Sixto; Durrant, James Royal Society of Chemistry (2020-08-10)Nickel oxide-based catalysts currently represent the state of the art in electrochemical water oxidation in alkaline pH. However, much of their functionality remains poorly understood, particularly regarding catalytically ... -
Spectroelectrochemical Analysis of the Water Oxidation Mechanism on Doped Nickel Oxides
Rao, Reshma R.; Corby, Sacha; Bucci, Alberto; García-Tecedor, Miguel; Mesa, Camilo A.; Rossmeisl, Jan; Gimenez, Sixto; Lloret Fillol, Julio; Stephens, Ifan; Durrant, James American Chemical Society (2022-04-20)Metal oxides and oxyhydroxides exhibit state-of-the-art activity for the oxygen evolution reaction (OER); however, their reaction mechanism, particularly the relationship between charging of the oxide and OER kinetics, ... -
Switchable All Inorganic Halide Perovskite Nanocrystalline Photoelectrodes for Solar-Driven Organic Transformations
Fernandez-Climent, Roser; Gualdrón Reyes, Andrés Fabián; García-Tecedor, Miguel; Mesa, Camilo A.; Cardenas-Morcoso, Drialys; Montañés, Laura; Barea, Eva M; Mas, Elena; Julian-Lopez, Beatriz; Mora-Sero, Ivan; Gimenez, Sixto Wiley (2021-10-30)All inorganic halide perovskite nanocrystals (NCs) are considered as fascinating materials for a wide range of optoelectronic applications encompassing photovoltaics, lasing, sensing, and photocatalysis due to their ... -
The role of crystal facets and disorder on photo-electrosynthesis
Pastor, Ernest; Montañés, Laura; Gutiérrez-Blanco, Ana; Hegner, Franziska; Mesa, Camilo A.; Lopez, Nuria; Gimenez, Sixto Royal Society of Chemistry (2022-09-23)Photoelectrochemistry has the potential to play a crucial role in the storage of solar energy and the realisation of a circular economy. From a chemical viewpoint, achieving high conversion efficiencies requires subtle ... -
UV-Vis operando spectroelectrochemistry for (photo)electrocatalysis: Principles and guidelines
Mesa, Camilo A.; Pastor , Ernest; Francàs Forcada, Laia Elsevier (2022-06-30)Electrocatalytic and photoelectrocatalytic technologies are key players in the transition to a circular economy. In order to rationally design the new generation of efficient (photo)electrocatalysts it is critical to ... -
Water oxidation kinetics of nanoporous BiVO4 photoanodes functionalised with nickel/iron oxyhydroxide electrocatalysts
Francàs Forcada, Laia; Selim, Shababa; Corby, Sacha; Lee, Dongho; Mesa, Camilo A.; Pastor , Ernest; Choi, Kyoung-Shin; Durrant, James Royal Society of Chemistry (2021-04-15)In this work, spectroelectrochemical techniques are employed to analyse the catalytic water oxidation performance of a series of three nickel/iron oxyhydroxide electrocatalysts deposited on FTO and BiVO4, at neutral pH. ...