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dc.contributor.authorHirst, Andrew R.
dc.contributor.authorMiravet, Juan F.
dc.contributor.authorEscuder, Beatriu
dc.contributor.authorNoirez, Laurence
dc.contributor.authorCastelletto, Valeria
dc.contributor.authorHamley, Ian W.
dc.contributor.authorSmith, David K.
dc.description.abstractTwo-component systems capable of self-assembling into soft gel-phase materials are of considerable interest due to their tunability and versatility. This paper investigates two-component gels based on a combination of a l-lysine-based dendron and a rigid diamine spacer (1,4-diaminobenzene or 1,4-diaminocyclohexane). The networked gelator was investigated using thermal measurements, circular dichroism, NMR spectroscopy and small angle neutron scattering (SANS) giving insight into the macroscopic properties, nanostructure and molecular-scale organisation. Surprisingly, all of these techniques confirmed that irrespective of the molar ratio of the components employed, the “solid-like” gel network always consisted of a 1:1 mixture of dendron/diamine. Additionally, the gel network was able to tolerate a significant excess of diamine in the “liquid-like” phase before being disrupted. In the light of this observation, we investigated the ability of the gel network structure to evolve from mixtures of different aromatic diamines present in excess. We found that these two-component gels assembled in a component-selective manner, with the dendron preferentially recognising 1,4-diaminobenzene (>70 %), when similar competitor diamines (1,2- and 1,3-diaminobenzene) are present. Furthermore, NMR relaxation measurements demonstrated that the gel based on 1,4-diaminobenzene was better able to form a selective ternary complex with pyrene than the gel based on 1,4-diaminocyclohexane, indicative of controlled and selective π–π interactions within a three-component assembly. As such, the results in this paper demonstrate how component selection processes in two-component gel systems can control hierarchical self-assembly.ca_CA
dc.format.extent7 p.ca_CA
dc.relation.isPartOfChemistry - A European Journal, 15, 2, p. 372–379ca_CA
dc.rightsCopyright © 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheimca_CA
dc.subjectsoft materialsca_CA
dc.titleSelf-Assembly of Two-Component Gels: Stoichiometric Control and Component Selectionca_CA

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