Listar QFA_Articles por autoría "0c5e20f0-0f49-4841-875e-f35a7180dc85"
Mostrando ítems 1-11 de 11
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Binuclear Sulfide Niobium Clusters Coordinated by Diimine Ligands: Synthesis, Structure, Photocatalytic Activity and Optical Limiting Properties
Rogachev, Alexander V.; Gushchin, Artem L.; Abramov, Pavel A.; Kozlova, Ekaterina A.; Vicent Barrera, Cristian; Piryazev, Dmitry; Barlow, Adam; Samoc, Marek; Humphrey, Mark G.; Llusar, Rosa; Fedin, Vladimir P.; Sokolov, Maxim Wiley (2015)Substitution reactions of binuclear niobium cluster anion [Nb2S4(NCS)8]4– with different types of pyridine-based diimine ligands have been carried out. In the case of 2,2′-bipyridine (bipy) and its derivatives, only ... -
Complexes of M3S44+ (M = Mo, W) with chiral alpha-hydroxy and aminoacids: Synthesis, structure and solution studies
Sokolov, Maxim; Adonin, Sergey A.; Virovets, Alexander V.; Abramov, Pavel A.; Vicent Barrera, Cristian; Llusar, Rosa; Fedin, Vladimir P. Elsevier (2013-01)New complexes of triangular clusters M3S4 4+ (M = Mo, W) with incomplete cuboidal metal–chalcogenide framework bearing chiral a-hydroxy and amino acids have been prepared. L-lactic acid (H2lac), L-mandelic acid (H2man), ... -
Cycloaddition of alkynes to diimino Mo3S4 cubane-type clusters: a combined experimental and theoretical approach
Pino Chamorro, Jose Angel; Laricheva, Yuliya A.; Guillamón, Eva; Fernández-Trujillo, M. Jesús; Bustelo, Emilio; Gushchin, Artem L.; Shmelev, Nikita Y.; Abramov, Pavel A.; Sokolov, Maxim; Llusar, Rosa; García Basallote, Manuel; Algarra, Andrés G. Royal Society of Chemistry (2016)A heterocyclic ligand 4,4′-di-tert-butyl-2,2′-bipyridine (dbbpy) has been coordinated to the Mo3S4 cluster unit affording the complex [Mo3S4Cl3(dbbpy)3]+ ([1]+) in a one-step ligand-exchange protocol from [Mo3S4(tu)8(H2O)]Cl4·4H2O ... -
First heteroleptic Mo3S7 clusters containing non-innocent phenanthroline ligands
Llusar, Rosa; Recatalá Ferrandis, David; Gushchin, Artem L.; Abramov, Pavel A. SP MAIK Nauka/Interperiodica (2012-03)Reaction of the thiobromide [Mo3S7Br6]2− cluster anion with 5,6-dimethyl-1,10-phenanthroline (Me2Phen) in solution leads to the substitution of two bromide ligands and the subsequent formation of a new mixed-ligand neutral ... -
Hemilability of phosphine-thioether ligands coordinated to trinuclear Mo3S4 cluster and its effect on hydrogenation catalysis
Gushchin, Artem L.; Shmelev, Nikita Y.; Malysheva, Svetlana F.; Artem’ev, Alexander V.; Belogorlova, Nataliya A.; Abramov, Pavel A.; Kompan’kov, Nikolay B.; Manoury, Eric; Poli, Rinaldo; Sheven, Dmitriy G.; Llusar, Rosa; Sokolov, Maxim Royal Society of Chemistry (2018)Ligand-exchange reactions of [Mo3S4(tu)8(H2O)]Cl44H2O (tu = thiourea) with (PhCH2CH2)2PCH2CH2SR ligands, where R = Ph (PS1), pentyl (PS2) or Pr (PS3) afford new complexes isolated as [Mo3S4Cl3(PS1)3]PF6 ([1]PF6), ... -
Heterometallic Cuboidal Clusters M3M‘Q4 (M = Mo, W; M‘= Sn, Pb, As, Sb; Q = S, Se): From Coordination Compounds to Supramolecular Adducts
Hernández Molina, Rita; Kalinina, Irina V.; Abramov, Pavel A.; Sokolov, Maxim; Virovets, Alexander V.; González Platas, Javier; Llusar, Rosa; Polo Ortiz, Victoriano; Vicent Barrera, Cristian; Fedin, Vladimir P. American Chemical Society (2008)Reactions of the incomplete cuboidal clusters [M3Q4(acac)3(py)3]+ (M = Mo, W; Q = S, Se) with group 14 and 15 metal complexes with the s2p0 electronic configuration (AsPh3, SbPh3, SbCl3, SbI3, PbI3-, SnCl3-) led to heterometal ... -
Homoleptic Molybdenum Cluster Sulfides Functionalized with Noninnocent Diimine Ligands: Synthesis, Structure, and Redox Behavior
Gushchin, Artem L.; Laricheva, Yuliya A.; Abramov, Pavel A.; Virovets, Alexander V.; Vicent Barrera, Cristian; Sokolov, Maxim; Llusar, Rosa Wiley (2014)Thiourea (tu) has been coordinated to the Mo3S44+ cluster unit to afford the new cluster compound [Mo3S4(tu)8(H2O)]Cl4·4H2O (1). The high substitutional lability of the thiourea ligands can be exploited to achieve smooth ... -
Kinetics Aspects of the Reversible Assembly of Copper in Heterometallic Mo3CuS4 Clusters with 4,4′-Di-tert-butyl-2,2′-bipyridine
Pino Chamorro, Jose Angel; Laricheva, Yuliya A.; Guillamón, Eva; Fernández-Trujillo, M. Jesús; Algarra, Andrés G.; Gushchin, Artem L.; Abramov, Pavel A.; Bustelo, Emilio; Llusar, Rosa; Sokolov, Maxim; García Basallote, Manuel American Chemical Society (2016)Treatment of the triangular [Mo3S4Cl3(dbbpy)3]Cl cluster ([1]Cl) with CuCl produces a novel tetrametallic cuboidal cluster [Mo3(CuCl)S4Cl3(dbbpy)3][CuCl2] ([2][CuCl2]), whose crystal structure was determined by X-ray ... -
Mo3Q7 (Q = S, Se) Clusters Containing Dithiolate/Diselenolate Ligands: Synthesis, Structures, and Their Use as Precursors of Magnetic Single-Component Molecular Conductors
Gushchin, Artem L.; Llusar, Rosa; Vicent Barrera, Cristian; Abramov, Pavel A.; Gómez García, Carlos J. WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim (2013-05)The coordination chemistry of dithiolene and diselenolene ligands towards the all-selenium [Mo3Se7Br6]2– dianion has been investigated. Complexes (nBu4N)2[Zn(dmit)2] (dmit = 1,3-dithia-2-thioxo-4,5-dithiolate) and ... -
Photogeneration of Hydrogen from Water by Hybrid Molybdenum Sulfide Clusters Immobilized on Titania
Recatalá Ferrandis, David; Llusar, Rosa; Gushchin, Artem L.; Kozlova, Ekaterina A.; Laricheva, Yuliya A.; Abramov, Pavel A.; Sokolov, Maxim; Gómez, Roberto; Lana-Villarreal, Teresa John Wiley & Sons (2015)Two new hybrid molybdenum(IV) Mo3S7 cluster complexes derivatized with diimino ligands have been prepared by replacement of the two bromine atoms of [Mo3S7Br6]2− by a substituted bipyridine ligand to afford heteroleptic ... -
Selective synthesis of triangular cluster oxido-sulfidocomplexes of Mo and W: High yield preparations of [Mo3O2S2(H2O)9]4+, [W3O2S2(H2O)9]4+, [W2MoO2S2(H2O)9]4+ and their derivatization
Abramov, Pavel A.; Sokolov, Maxim; Hernández Molina, Rita; Vicent Barrera, Cristian; Virovets, Alexander V.; Naumov, Dmitry Yu; Gili, Pedro; González Platas, Javier; Fedin, Vladimir P. Elsevier (2010)Reaction of [Mo2O2(μ-S)2(H2O)6]2+ with Mo(CO)6 or metallic Mo under hydrothermal conditions (140 °C, 4 M HCl) gives oxido-sulfido cluster aqua complex [Mo3(μ3-S)(μ-O)2(μ-S)(H2O)9]4+ (1). Similarly, [W3(μ3-S)(μ-O)2(μ-S)(H2O)9]4+ ...