Mostrar el registro sencillo del ítem
Use fluorescence spectroscopy to study polymeric materials with porous structure based on imprinting by self-assembled fibrilar networks
dc.contributor.author | Burguete, M. Isabel | |
dc.contributor.author | Galindo, Francisco | |
dc.contributor.author | Gavara, Raquel | |
dc.contributor.author | Izquierdo Arcusa, María Ángeles | |
dc.contributor.author | Lima, Joao C. | |
dc.contributor.author | Luis, Santiago V. | |
dc.contributor.author | Parola, A. Jorge | |
dc.contributor.author | Pina, Fernando | |
dc.date.accessioned | 2013-10-14T12:05:49Z | |
dc.date.available | 2013-10-14T12:05:49Z | |
dc.date.issued | 2008 | |
dc.identifier.citation | Langmuir, 24, 17, p. 9795–9803 | ca_CA |
dc.identifier.issn | 0743-7463 | |
dc.identifier.uri | http://hdl.handle.net/10234/74166 | |
dc.description.abstract | Different polymeric materials have been prepared from the organogels formed by a polymerizable methacrylic mixture (methyl methacrylate/ethylene glycol dimethacrylate, 1:1, w/w) and the macrocyclic pseudopeptide 1. The use of (2,4,6-trimethylbenzoyl)diphenylphosphine oxide as a very efficient radical initiator allows polymeric materials in which the structure of the fibrils formed by self-assembly of the organogelator 1 is truly preserved to be obtained. Removal of the pseudopeptidic molecule provides materials with a porous structure reflecting that of the original self-assembled fibrils. The use of fluorescent probes such as rhodamine B and pyrene greatly facilitate the study of the porous structures formed and, accordingly, that of the morphology of the original fibrils. Those studies reveal the presence of a permanent porosity and the organization of the substructures as a porous network. This confirms the existence of a nucleation and growth mechanism for the generation of the fibrils, giving rise to the formation of spherulitic structures. Those spherulites are additionally linked by connections of variable size. A series of diffusion experiments allowed establishment of a direct dependence of the inner porosity of the materials on the amount of self-organizing template used for their preparation. | ca_CA |
dc.format.extent | 9 p. | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | American Chemical Society | ca_CA |
dc.rights | Copyright © 2008 American Chemical Society | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | ABS resins | ca_CA |
dc.subject | Ethylene glycol | ca_CA |
dc.subject | Fluorescence | ca_CA |
dc.subject | Luminescence | ca_CA |
dc.subject | Surface treatment | ca_CA |
dc.title | Use fluorescence spectroscopy to study polymeric materials with porous structure based on imprinting by self-assembled fibrilar networks | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1021/la801342f | |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
dc.relation.publisherVersion | http://pubs.acs.org/doi/abs/10.1021/la801342f | ca_CA |
Ficheros en el ítem
Ficheros | Tamaño | Formato | Ver |
---|---|---|---|
No hay ficheros asociados a este ítem. |
Este ítem aparece en la(s) siguiente(s) colección(ones)
-
QUIO_Articles [690]
Articles de publicacions periòdiques