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Short, Stereoselective Synthesis of the Naturally Occurring Pyrrolidine Radicamine B and a Formal Synthesis of Nectrisine
dc.contributor.author | Ribés Vidal, Celia | |
dc.contributor.author | Falomir, Eva | |
dc.contributor.author | Carda, Miguel | |
dc.contributor.author | Marco, J. Alberto | |
dc.date.accessioned | 2013-10-07T10:53:39Z | |
dc.date.available | 2013-10-07T10:53:39Z | |
dc.date.issued | 2008 | |
dc.identifier.citation | Journal of Organic Chemistry, 73, 19, p. 7779–7782 | ca_CA |
dc.identifier.issn | 0022-3263 | |
dc.identifier.uri | http://hdl.handle.net/10234/73886 | |
dc.description.abstract | A short, stereoselective synthesis of the naturally occurring pyrrolidine radicamine B is reported. Garner′s (R)-aldehyde, prepared from d-serine, was the chiral starting material. The pyrrolidine ring was stereoselectively created in a very efficient way through a five-step, one-pot transformation. In addition, an intermediate of this synthesis was transformed into an intermediate of a previously published synthesis of the potent α-glucosidase inhibitor nectrisine. | ca_CA |
dc.format.extent | 4 p. | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | American Chemical Society | ca_CA |
dc.rights | Copyright © 2008 American Chemical Society | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | Aldehydes | ca_CA |
dc.subject | Stereochemistry | ca_CA |
dc.subject | Chemical reactions | ca_CA |
dc.subject | Organic compounds | ca_CA |
dc.title | Short, Stereoselective Synthesis of the Naturally Occurring Pyrrolidine Radicamine B and a Formal Synthesis of Nectrisine | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1021/jo8012989 | |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
dc.relation.publisherVersion | http://pubs.acs.org/doi/abs/10.1021/jo8012989 | ca_CA |
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