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Supramolecular Interactions Based on Ionic Liquids for Tuning of the Catalytic Efficiency of (L)-Proline
(American Chemical Society, 2016-09)
Noncovalent intermolecular interactions between (l)-proline and ionic liquids (ILs) are key to explain the different catalytic efficiencies observed for this organocatalyst in the aldol reaction carried out in ILs or in ...
Catalytic Hydrodefluorination with Late Transition Metal Complexes
(ACS Publications, 2014-08-07)
This perspective article focuses its attention on the most recent advances in hydrodefluorination processes catalyzed by late transition metal complexes, a field that has been a matter of increasing interest during the ...
Ferrocenyl-Imidazolylidene Ligand for Redox-Switchable Gold-Based Catalysis. A Detailed Study on the Redox-Switching Abilities of the Ligand
(American Chemical Society, 2016)
An imidazolium salt with a fused benzoferrocenyl was synthesized. This compound was used as an N-heterocyclic carbene (NHC) precursor, and the related ferrocenyl-imidazolylidene complexes Fc-NHC-MLn (MLn = IrCl(COD), ...
Pd catalysts immobilized onto gel-supported ionic liquid-like phases (g-SILLPs): A remarkable effect of the nature of the support
(Elsevier, 2010)
New polymeric materials containing functional sites analogous to ionic liquids have been synthesized. Those materials are a supported reservoir for the active Pd species. Their catalytic activity has been evaluated for the ...
Experimental and Theoretical Approaches to the Influence of the Addition of Pyrene to a Series of Pd and Ni NHC-Based Complexes: Catalytic Consequences
(Wiley, 2014-11-20)
A series of Ni and Pd complexes with three different N-heterocyclic carbene (NHC)-based ligands (imidazolylidene, benzimidazolylidene and pyrene–imidazolylidene) has been prepared and fully characterized. The influence of ...
Insight into the esterase like activity demonstrated by an imidazole appended self-assembling hydrogelator
(Royal Society of Chemistry, 2016)
A low molecular weight hydrogelator with a covalently appended imidazole moiety is reported. Capable of percolating water in the pH range of 6 to 8, it proves to be an efficient catalyst upon self-assembly, showing ...
Supercritical Synthesis of Biodiesel
(MDPI Publishing, 2012)
The synthesis of biodiesel fuel from lipids (vegetable oils and animal fats) has gained in importance as a possible source of renewable non-fossil energy in an attempt to reduce our dependence on petroleum-based fuels. The ...
Recent developments in the applications of palladium complexes bearing N-heterocyclic carbene ligands
(Bentham Science Publishers, 2011-01-09)
N-heterocyclic carbene (NHC) ligands have become ubiquitous ligands in the preparation of metal complexes with new catalytic applications. Mainly due to their applications in C-C bond formation reactions, a plethora of ...
Polymer-supported ionic-liquid-like phases (SILLPs): transferring ionic liquid properties to polymeric matrices
(Wiley, 2011-01-12)
The physico-chemical properties of polymers with ionic-liquid-like moieties covalently bound to their surfaces (SILLPs) have been studied by thermal and spectroscopic techniques, as well as by direct impedance and dielectric ...
A Simple Route to Chelating, Structurally Different Triazole-Based Bis(N-heterocyclic carbene) Ligands and Their Coordination to PtIl
(Wiley, 2011-01)
Two new bis(triazolium) salts have been prepared and used as N-heterocyclic carbene (NHC) precursors. The structure of the salts is highly dependent on the synthetic route, which implies the sequential alkylation of two ...