Iron(II) Complexes Bearing Chelating Cyclopentadienyl-N-Heterocyclic Carbene Ligands as Catalysts for Hydrosilylation and Hydrogen Transfer Reactions
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Otros documentos de la autoría: Kandepi, V. V. Krishna Mohan; Cardoso, João M. S.; Peris, Eduardo; Royo, Beatriz
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http://dx.doi.org/10.1021/om100246j |
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Título
Iron(II) Complexes Bearing Chelating Cyclopentadienyl-N-Heterocyclic Carbene Ligands as Catalysts for Hydrosilylation and Hydrogen Transfer ReactionsFecha de publicación
2010Editor
American Chemical SocietyISSN
0276-7333Cita bibliográfica
Organometallics (2010), 29, 12, p. 2777-2782Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://pubs.acs.org/doi/abs/10.1021%2Fom100246jResumen
A series of piano-stool iron(II) complexes bearing bidentate cyclopentadienyl-functionalized N-heterocyclic carbene ligands (Cp-NHC)Fe(CO)I (Cp = substituted and unsubstituted cyclopentadienyl) have been prepared upon ... [+]
A series of piano-stool iron(II) complexes bearing bidentate cyclopentadienyl-functionalized N-heterocyclic carbene ligands (Cp-NHC)Fe(CO)I (Cp = substituted and unsubstituted cyclopentadienyl) have been prepared upon reaction with Fe(CO)4I2 and characterized by spectroscopic and crystallographic methods. The 16-electron half-sandwich compound (Cp*-NHC)FeCl (Cp* = η5-C5Me4) has been synthesized by using FeCl2 as precursor material. The new iron complexes displayed good catalytic activity in catalytic transfer hydrogenation of ketones and hydrosilylation reactions. [-]
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