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Sulfonate-Functionalized NHC-Based Ruthenium Catalysts for the Isomerization of Allylic Alcohols in Water. Recyclability Studies
dc.contributor.author | Azua Barrios, Arturo | |
dc.contributor.author | Sanz, Sergio | |
dc.contributor.author | Peris, Eduardo | |
dc.date.accessioned | 2012-12-03T16:11:56Z | |
dc.date.available | 2012-12-03T16:11:56Z | |
dc.date.issued | 2010 | |
dc.identifier.citation | Organometallics (2010), 29, 16, p. 3661-3664 | ca_CA |
dc.identifier.issn | 0276-7333 | |
dc.identifier.uri | http://hdl.handle.net/10234/52682 | |
dc.description.abstract | Two new complexes of the type [Ru(CO3)(η6-arene)(NHC)]Cs, in which the NHC ligand incorporates a sulfonate functionality, have been prepared and fully characterized. The two water-soluble complexes have been tested in the catalytic isomerization of allylic alcohols in water. The p-cymene compound (labeled as 1) was shown to be an excellent catalyst when compared to other related Ru catalysts. This catalyst can be recycled by simple liquid−liquid extractions several times without detected loss of activity. | ca_CA |
dc.format.extent | 4 p. | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | American Chemical Society | ca_CA |
dc.rights | Copyright © 2010 American Chemical Society | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.title | Sulfonate-Functionalized NHC-Based Ruthenium Catalysts for the Isomerization of Allylic Alcohols in Water. Recyclability Studies | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1021/om100601r | |
dc.rights.accessRights | info:eu-repo/semantics/closedAccess | ca_CA |
dc.relation.publisherVersion | http://pubs.acs.org/doi/abs/10.1021%2Fom100601r | ca_CA |
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