Efficient and selective chemical transformations under flow conditions: the combination of supported catalysts and supercritical fluids
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Otros documentos de la autoría: Burguete, M. Isabel; Garcia-Verdugo, Eduardo; Luis, Santiago V.
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Mostrar el registro completo del ítemcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
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Título
Efficient and selective chemical transformations under flow conditions: the combination of supported catalysts and supercritical fluidsFecha de publicación
2011-09-30Editor
Beilstein InstitutISSN
1860-5397Cita bibliográfica
Beilstein Journal of Organic Chemistry (2011) vol. 7, p. 1347–1359Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://www.beilstein-journals.org/bjoc/content/pdf/1860-5397-7-159.pdfPalabras clave / Materias
Resumen
This paper reviews the current trends in the combined use of supported catalytic systems, either on solid supports or in liquid phases and supercritical fluids (scFs), to develop selective and enantioselective chemical ... [+]
This paper reviews the current trends in the combined use of supported catalytic systems, either on solid supports or in liquid phases and supercritical fluids (scFs), to develop selective and enantioselective chemical transformations under continuous and semi-continuous flow conditions. The results presented have been selected to highlight how the combined use of those two elements can contribute to: (i) Significant improvements in productivity as a result of the enhanced diffusion of substrates and reagents through the interfaces favored by the scF phase; (ii) the long term stability of the catalytic systems, which also contributes to the improvement of the final productivity, as the use of an appropriate immobilization strategy facilitates catalyst isolation and reuse; (iii) the development of highly efficient selective or, when applicable, enantioselective chemical transformations. Although the examples reported in the literature and considered in this review are currently confined to a limited number of fields, a significant development in this area can be envisaged for the near future due to the clear advantages of these systems over the conventional ones. [-]
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info:eu-repo/semantics/openAccess
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