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dc.contributor.authorNuevo, Daniel
dc.contributor.authorPoyatos, Macarena
dc.contributor.authorPeris, Eduardo
dc.date.accessioned2019-02-01T12:12:10Z
dc.date.available2019-02-01T12:12:10Z
dc.date.issued2018
dc.identifier.citationNUEVO, Daniel; POYATOS, Macarena; PERIS, Eduardo. A Dinuclear Au (I) Complex with a Pyrene-di-N-heterocyclic Carbene Linker: Supramolecular and Catalytic Studies. Organometallics, 2018.ca_CA
dc.identifier.issn0276-7333
dc.identifier.issn1520-6041
dc.identifier.urihttp://hdl.handle.net/10234/180560
dc.description.abstractA digold(I) complex with a pyrene-di-N-heterocyclic carbene ligand has been obtained and fully characterized. The host–guest properties of the complex were studied in chloroform with a series of polycylic aromatic hydrocarbons (PAHs), and the association constants were determined. The affinity increases with the size of the PAH, with a maximum binding constant of 105 M–1 for the aggregation with coronene. The catalytic activity of the complex was tested in the hydroamination of phenylacetylene with three different amines. The studies showed that the addition of coronene to the reaction medium produces an enhancement of about 20–30% in the activity of the complex.ca_CA
dc.format.extent5 p.ca_CA
dc.format.mimetypeapplication/pdfca_CA
dc.language.isoengca_CA
dc.publisherAmerican Chemical Societyca_CA
dc.relation.isPartOfOrganometallics 2018, 37, 20.ca_CA
dc.rightsCopyright © 2018 American Chemical Societyca_CA
dc.titleA Dinuclear Au(I) Complex with a Pyrene-di-N-heterocyclic Carbene Linker: Supramolecular and Catalytic Studiesca_CA
dc.typeinfo:eu-repo/semantics/articleca_CA
dc.identifier.doihttps://doi.org/10.1021/acs.organomet.8b00087
dc.relation.projectIDCTQ2014-51999-P ; UJI-B2017-07 ; P11B2015-24 ; P11B2014-02ca_CA
dc.rights.accessRightsinfo:eu-repo/semantics/restrictedAccessca_CA
dc.relation.publisherVersionhttps://pubs.acs.org/doi/10.1021/acs.organomet.8b00087ca_CA
dc.type.versioninfo:eu-repo/semantics/publishedVersionca_CA


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