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Attempt synthesis of IR (I) metal complexes for catalytic conversion of glycerol to lactic acid
dc.contributor.author | Vicente Pérez, Nuria | |
dc.contributor.other | Guisado Barrios, Gregorio | |
dc.contributor.other | Universitat Jaume I. Departament de Química Inorgànica i Orgànica | |
dc.date.accessioned | 2018-10-01T07:00:21Z | |
dc.date.available | 2018-10-01T07:00:21Z | |
dc.date.issued | 2018-07 | |
dc.identifier.uri | http://hdl.handle.net/10234/176394 | |
dc.description | Treball Final de Grau en Química. Codi: QU0943. Curs acadèmic: 2017/2018 | ca_CA |
dc.description.abstract | The aim of this research work is the synthesis of two novel iridium complexes containing mesoionic triazolylidene ligands. The ultimate goal would imply the evaluation of their performance in a very challenging transformation such as the catalytic conversion of glycerol to lactic acid. The synthesis of the iridium complexes involves the synthesis of the ligand salt precursors that will afford the desired corresponding metal complexes after deprotonation. Herein, two bistriazolium salts will be prepared. They are ready available after alkylation of the related bistriazole that can be obtained on big scale from ready available compounds. To acquire new skills through the search and use scientific articles from different resources that can be used for the design and synthesis of compounds that have not been described in the literature. On the other hand, there are other types of objectives in the realization of this research work, such as gaining experience in a research laboratory, learning the use of some of the most commonly used techniques in an Organometallic laboratory. Among them, is the use of Schlenk techniques working with a glass manifold that allows to work under strict inert conditions, but also the use of liquid nitrogen to carry out reactions at very low temperature. To get familiar with the use of characterization techniques such as NMR and HR-MS spectroscopy. In addition, improve skills in interpreting the results obtained in NMR spectroscopy and mass spectroscopy. | ca_CA |
dc.format.extent | 51 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Universitat Jaume I | ca_CA |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | Grau en Química | ca_CA |
dc.subject | Grado en Química | ca_CA |
dc.subject | Bachelor's Degree in Chemistry | ca_CA |
dc.title | Attempt synthesis of IR (I) metal complexes for catalytic conversion of glycerol to lactic acid | ca_CA |
dc.type | info:eu-repo/semantics/bachelorThesis | ca_CA |
dc.educationLevel | Estudios de Grado | ca_CA |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
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